学位论文_金属酞菁与纳米二氧化锰二元体系的电催化氧还原性能研究 .docVIP

分类号 作 者 单 位 指 导 老 师 作 者 姓 名 专 业、班 级 提 交 时 间 二 〇年 六 月 大环化合物如酞菁( Pc) 、四甲氧基苯基卟啉( TMPP) 、四苯基卟啉( TPP) 等具有多齿配位作用及大环结构特征, 可以与过渡金属离子M ( M =Fe、Co、Ni)形成过渡金属大环化合物。 该类大环化合物具有高的共轭结构和化学稳定性且对分子氧还原表现出良好的电催化活性, 因而在催化剂领域被广泛研究。羧基金属酞菁是以偏苯三甲酸酐、MCl2(M=Fe ，Co，Ni )、尿素及钼酸铵为原料，采用熔融法合成的2，9，16，23一四羧基金属酞菁。此类过渡金属大环配合物酞菁配合物对分子氧的还原反应具有很高的电催化活性。 以提高催化剂的催化性能为目的，将二氧化锰和金属酞菁配成适当溶液进行电化学实验。本文主要应用循环伏安法和线性扫描法研究了金属铁酞菁、钴酞菁和镍酞菁与二氧化锰以不同比例配制的溶液在KOH溶液中对氧电化学行为，以修饰电极和气体扩散电极为工作电极、铂电极为辅助电极、饱和甘汞电极为参比电极的三电极体系中考察和比较了制备的各种修饰电极和气体扩电极对氧还原的电催化性能。该实验保持载体和催化剂的总量不变，采用等摩尔（质量）连续变化法改变俩种催化剂比例，通过测试不同比例的样品催化性能，选取两种催化剂的最佳比例。 Abstract Macrocyclic compounds (such as phthalocyanine ( Pc ), tetramethoxyphenyl porphyrin ( TMPP ), tetraphenyl porphyrin ( TPP ) etc.) with Multidentate coordination effect and large ring structure, with the transition metal ions M ( M =Fe, Co, Ni) form the transition metal macrocyclic compound. The compounds have high conjugated structure and chemical stability and the reduction of molecular oxygen showed good electrocatalytic activity, therefore is widely researched in catalyst. Carboxyl metal phthalocyanine with trimellitic anhydride ( M=Fe, Co, Ni ), urea and ammonium molybdate as the raw material, adopting melting synthesis of 2,9,16,23 one four carboxyl metal phthalocyanine. This kind of transition metal acrocyclic complexes of phthalocyanines on molecular oxygen reduction reaction with high catalytic activity. In order to improve the catalytic performance of the catalyst for the purpose, manganese dioxide and metal phthalocyanine with appropriate solution for electrochemical experiments. This paper applied cyclic voltammetry and linear scanning method of metal, iron phthalocyanine cobalt phthalocyanine and nickel phthalocyanine and manganese dioxide with different proportion of solution prepared in KOH solution on oxygen electrochemical behavior, with modified electrode and gas diffusion electrode as working electrode, platinum as auxili