SnO2基固溶体用于甲烷深度氧化：X射线衍射外推法测定 SnO2晶格容量.pdfVIP

Chin臼e Journal ofCatalysis 37 (2016) 1293- 1302 催化学报2016年第37卷第8期 1 available at www.sciencedirec t. com .-;~ .; ScienceDirect ELSEVIER journal homepage: /locate/chnjc Article Sn02-based solid solutions for CH4 deep oxidation: Quantifying the lattice capacity of Sn02 using an X-ray diffraction extrapolation method Qi Sun t ,Xianglan Xu t , Honggen Peng, Xiuzhong Fang, Wenming Liu, Ji awei Ying, Fan Yu, XiangWang* Cou，哩geofChemis町I Nanchang University, Nanchαng330031，j.阳ng.川 China ART I CLE INFO ABSTRACT Articlehisωry: A seri臼 of Sn02-based cataly筑s modified by Mn, Zr, Ti and Pb oxides wi址1 a Sn/M (M = Mn, Zr, Ti Received 28 February 2016 and Pb) molar ratio of9/1 were prepared by a co-precipitation method and 田ed for CH4 and CO 3 Accep恒d 22 April2016 oxidation. The Mn Zr4飞Ti轩 and Pb轩臼tions are incorporated into 也e lattice of tetragonal rutile 飞 Published 5 August 2016 Sn?2 ωform a solid solution s仿ucture. As a ∞nsequence， the surface area and 仕lermal stability of the catalysts are improved. Moreover, the 。巧gen species of the modified catalysts become easier ω be reduced. Therefore， 也e oxidation activity over the 臼talysts was improved, except for the one K哩ywords: Sn02-based solid solution modified by Pb 。到de. M缸理由lese oxide demonstrates 出e best promotional effects for Sn02. Using X-raydi街actione由呻olat