甲壳素对铅（Ⅱ）的吸附研究.pdfVIP

??25???3?? ?? ? ?? ?? ?? ? ?? Vo1??25??No??3 2013?? 3?? ChemicalResearchandApplication Mar????2013 ???±???1004??1656(2013)03-0336-04 ??????? (??)???????о? ?????h??????? ??????? (1????????????????? ??? 323000??2???????????????????? ??? 316004) ?????????????????????????????????飬????????? pH=4??46???????????t?????????????? ?478mg??g (???)????0??5mol??L HC1????????????98??8????????????????k298=8??53~10??s?????? ?????E=16??54kJ??otol???????????????? Freundlich????????????????????AH=8??70kJ??mol????AS= 41??7J ??mol? ??K????AG???3??71kJ ??otol???? ????????????? (II)?????? ?????????0647??3 ????????A Adsorptionbehaviorofchitinforlead(II) SHILin??meih ??WANGHui??jun??GAOWei??biao (1??LishuiTechonologyCollege??Lishui323000??Chian?? ?? 2??MarineScienceCollegeofZhejiangOceanUniversity??Zhoushna 316004??China) Abstract??TheadsorptionbehaviorofchitinforPb??isinvestigated??ChitinhasagoodadsorptionabilityforPb??intheHAc??NaAc medium atpH=4??56Thesmticallysaturatedsoprtioncapacityis478s??g ??resin??Pb??adsorbedonchitincanbeelutedquantitative?? lybyusing0??5mol??Lhydrochloricacidasaneluant??Theapparentrateconstantisk298=8??53x10 S????Theapparentactivationen?? ergyofchitinofrpb2 is16 ?? 54kJ ??mol????Theadsoprtionbehaviorchitinofrpb2 obeystheFreundlichisotherm??Theadsoprtion ~emr adynamicparametersofchitinofrpb2 areenthalpychna geAH=8 ?? 70kJ ??mol????freeenergychangeAC=?3??7lkJ ??otol_???? entropychangeAS=41??7J ??mol?? ??K???? Keywords??chitin??lead(II)??adsoprtionbehavior ?????????????????????ж?????? ???????й??N??O??P????????Щ?????? ????????????????????????а????????? ????о??????I??J