纳米尺度PtSiO2催化剂的制备及其催化合成对氨基苯酚反应研究.pdfVIP

纳米尺度Pt/SiO 催化剂的制备及其催化合成对氨基苯酚反 2 应研究 * 高杨，王淑芳,王延吉 ，赵新强 (河北工业大学 绿色化工与高效节能河北省重点实验室，天津300130) 摘要：于反相微乳液体系中，采用重新分散沉积负载法和改进的微乳-溶胶凝胶负载法制备了负载型Pt/SiO2 催化剂，并将其用于硝基苯加氢合成对氨基苯酚反应。结果表明，与相同条件下采用重新分散沉积负载法 制备的催化剂相比，微乳-溶胶凝胶负载法制备的催化剂， Pt 粒子在载体表面分散的要更加均匀，且粒径 较小。催化剂制备过程中加入一定量的草酸，可降低微核内 Pt 一次粒子的聚集程度，使负载后催化剂 Pt 粒径明显减小。通过改变水池中氯铂酸浓度可以实现具有不同 Pt 粒径催化剂的可控制备。以 Pt/SiO2 和 S2O82-/ZrO2 固体酸为催化剂进行的非酸介质中硝基苯加氢合成对氨基苯酚反应结果表明，该反应过程属结 构敏感型反应过程，随着Pt 粒径减小，硝基苯转化率及产品PAP 收率和选择性均明显提高,PAP 最高收率 为48.5% 。 关键词：铂纳米颗粒；负载型催化剂；微乳液；对氨基苯酚；硝基苯；加氢；S2O82-/ZrO2 固体酸 中图分类号： O643 文献标识码：A Preparation of Supported Pt nano-Particles Catalysts and its catalytic performance for Synthesis of p -Aminophenol * GAO yang, WANG Shufang, WANG Yanji , ZHAO Xinqiang Key Lab of Green Chemical Technology High Efficient Energy Saving of Hebei Province, Hebei University of Technology, Tianjin, P R China Abstract ：Silica-supportd platinum-based catalysts with different Pt particle size have been prepared in reverse microemulsion with redispersion method and improved microemulsion coupling with sol-gel process. The catalysts were tested in the reaction of nitrobenzene hydrogenation to p -aminophenol (PAP) in non-acid medium. It shows that the Pt particles on the catalyst prepared by improved microemulsion coupling sol-gel process is small and well dispersed. Adding a certain amount of oxalic acid in the solution of H2PtCl6 can decrease the aggregation of Pt particles in water pools and reduce Pt particle size on the catalysts. The Pt particle size of the catal