MolecularDevices.pptVIP

Molecular Devices 台大化工所 碩二 翁瑩倫 Group5 Nano Devices Molecular Devices Two terminal devices (報告以此為主) Wires Rectifying diodes Diodes exhibiting Negative Differential Resistance (NDR) Resistor Three terminal devices Chemical synthesis possible Electrical testing is quite difficult Bottom-up method on the nanometer scale Chemical Synthesis Break Junction Nanopore Wire(1) Are single molecular wire conducting? Wire(2) Molecular Wire (可以做很長) Diode(1) A novel fabrication technique to directly measure the conduction through a small number of organic molecules. These devices consist of a self-assembled monolayer (SAM) of conjugated molecular wires sandwiched between top and bottom metallic contact. Using the nanopore process and 4-thioacetylbiphenyl SAM we constructed a diode. Diode(2) . Switch(1) Use the nanopore process and 2’-amino-4,4’-di(ethynylphenyl)-5’-nitro-1-benaenthiolate (1a)SAM→low temperature negative differential resistance(NDR) Switch(2) This device work as two terminal switches: at a specific applied voltage current will flow (device ON) at all other voltage values current does not flow (device OFF) Switch(3) Use the nanopore process and 4,4’-di(ethynylphenyl)-2’-nitro-1-benaenthiolate (4a) SAM→room temperature negative differential resistance(NDR) Switch(4) The Switching Mechanism Memory cell(1) Use the nanopore process and molecular (1)~(3) in right Fig.(a)→room temperature memory cell which can be configured as a RAM Memory cell(2) Other Molecular Devices Note 本次報告大多以James M. Tour 和 Mark A. Reed的研究為主，他們做的分子是linear molecules containing phenylene and ethynylene units on either side of a central nitro- amino- or nitrophenylene moiety。 Metzger 也寫許多paper有關the molecular rectifier hexadecylquinolinolinium tricyanoquinodimethanide，是另一類分子。Ref. Ron Dagani, ‘Taking Baby Steps to “Moletronics”’ Jan.3 2000 CEN. 還有一類的分子元件是Electromechanical Molecular Electronic Devices，本次報告沒有詳盡介紹，其說明於D. Goldhaber-Gordon et al. Proceedings of