负载金属氧化物的活性炭纤维的制备及其脱硫性能的研究+.pdfVIP

C047 负载金属氧化物的活性炭纤维的制备 及其脱硫性能的研究 王建英 和 辉 胡永琪* 刘润静 赵瑞红 (河北科技大学化学与制药工程学院，河北石家庄，050018) 关键词：活性炭纤维；结构；表面形态；表面改性；脱硫 PREPARATION OF METAL DISPERSED ACTIVATED CARBON FIBERS AND THEIR APPLICATION FOR REMOVAL OF SO2 Wang Jianying, He Hui, Hu Yongqi *, Liu Runjing, Zhao Ruihong (College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang Hebei, 050018,PR China) Abstract Metal-loaded viscose rayon-based activated carbon fiber (VACF) and Pitch-based activated carbon fiber (PACF) were prepared by impregnating VACF and PACF with aqueous solution of metal compounds and subsequent heat treatment. The prepared samples were characterized by N2 adsorption at 77K and scanning electronic microscope (SEM). All the prepared samples showed an increase in specific surface area and total pore volume, and a little change in micropore size distribution in the course of an impregnation and subsequent heat treatment. The surfaces of the metal-loaded samples were rougher than that of as-received ACFs. SO2 removal activity at 45 ℃ of all the prepared samples were studied. Correlating the activity of SO2 removal with the pore structural parameters and the species of metal, it can be found that the physical properties of the prepared samples (M-ACFs) are unimportant in determining its desulfurization activity, while the species of metal loaded on ACF play an important role on SO2 removal activity. Keywords Activated carbon fibers, Structure, Surfacr morphologies, Surface modification, Desulfurization 引 言 众所周知，SO 是污染空气的最大有害成分，是形成酸雨的主要因素，如何有效地降低 2 其排放一直是环保领域研究的热点。利用活性炭吸附脱除烟气中的SO2 ，在治理大气污染的 同时还可回收硫资源，是一