金属有机分子筛Cu3BTC2在苯甲醇氧化反应中的催化性能.pdfVIP

石油学报(石油加工) 2008年10月 ACTA PETROLEI SINICA(PETROLEUM PROCESSING SECTION) 增刊 文章编号：1001—8719(2008)增刊-0204—04 金属有机分子筛Cu3【BTC)2在苯甲醇氧化 反应中的催化性能 任 蕾1，于 凯2，石秀峰1，李玉，；：平1，范彬彬，，窦 涛- (1．太原理工大学精细化工研究所，山西太原030024；2．太原理工大学煤科学与技术教育部重点实验室，山西太原030024) 摘要：在不同溶剂热反应条件下制备了具有自组装活性中心的金属有机分子筛Cu。(BTC)z，采用XRD和SEM 等手段对所制备的Cu。(BTC)z进行了表征，并考察了其在苯甲醇氧化反应中的催化性能。结果表明， Cu。(BTC)z可有效催化苯甲醇氧化反应，在相同的反应条件下，其催化活性高于离子交换法制备的Cu／Y催化 剂。Cu。(BTC)z的反应活性和稳定性与反应溶剂的选择有着密切的关系I反应后的Cu。(BTC)z虽然拓扑结构、 晶体形貌发生了一定变化，但反应活性仍然保持不变，在丙酮溶剂中重复使用的Cu。(BTC)。甚至表现出高于第 一次使用时的反应活性。 关键词：金属有机分子筛I Cu，(BTC)2#苯甲醇氧化 中图分类号：TQ032 文献标识码：A CATALYTIC PERFoRMANCE oF METALL0_．oRGAN IC MOLECULAR SlEVE Ca3(BTC)2 IN BENZYL ALCOHoL OXIDATIoN REN Leil，YU Kai2，SHI Xiu—fen91，LI Yu-pin91，FAN Bin-binl，DOU Ta01 (1．Institute of Special Chemicals，Taiyuan University of Technology，Taiyuan 030024，China； 2．KeyLaboratory ofCoal Science and Technology，TaiyuanUniversity ofTechnology，Taiyuan 030024·China) Abstract：Metallo-organic molecular sieve Cu3(BTC)2(BTC=benzene 1，3，5一tricarboxylate)，with self_organization active centres，was synthesized under different solvothermal reaction conditions．The synthesized samples were characterized by means of X—ray diffraction(XRD)and scanning electron microscopy(SEM)．Moreover，their catalytic properties in the oxidation of benzyl alcohol were also investigated in detail．The results indicated that Cu3(BTC)2 could effectively catalyze benzyl alcohol oxidation and exhibited higher catalytic activity than Cu(II)一 exchanged zeolite Y under the identical reaction conditions．The natures of reaction solvents had great influence on the catalytic activity and stability of Cu3(BTC)2．A structural and morphological change was observed during the reaction，but the reused catalyst still kept its original catalytic activity and even had higher activity than that ot the fresh sample in acetone solvent． Key words；metallo-organic molecular sieve；Cus(BTC)2；benzyl alcohol oxidation 分子筛材料正从传统的分子筛走向金属有机多 孔骨架化合物(MOFs)。金属有机多孔骨架化合物 又称金属有机分子筛是由金属离子和有机配体桥联 形成‘1_3]。近十年