压痕-急冷技术表征Co包覆Al2O3TiC复合材料的抗热震性能.pdfVIP

第22卷第1期 2007年1月 无机材料学报 Journal of Inorganic Materials V01．22．No．1 Jan．，2007 文章编号：1000—324X(2007)01—0106—07 压痕一急冷技术表征Co包覆A1203／TiC复合材料的 抗热震性能 师瑞霞1，李嘉1，王冬至1，尹衍升2 (1．济南大学材料学院，济南250022；2．中国海洋大学材料学院，青岛266003) 摘要：采用压痕一急冷技术测试了A1203／TiC(AT)和Co包覆A1203／TiC(ATC)两种复合材料的抗热震性能． 实验结果表明，ATC复合材料的抗裂纹扩展能力与抗循环热震性能都优于AT，ATC的临界温差△正比AT高 250C．诸抗热震参数R、R7、Rw和R。t的计算结果也表明，ATC的抗热震断裂能力和抗热震损伤能力均高于 AT．少量Co的添加，虽然对ATC复合材料的热物理参数改变很小，甚至可以忽略，但却大幅度提高了复合材料 的抗弯强度和断裂韧性，因而ATC具有较高的抗热震参数． ATC复合材料较好的抗热震性主要是其较高的抗 弯强度及断裂韧性的贡献． 关 键 词：压痕一急冷技术；抗热震性；Co包覆A1203／TiC复合材料；抗热震参数 中图分类号：TQl74 文献标识码：A Thermal Shock Resistance of Cobalt—coated A1203／TiC Composites Evaluated by Indentation-quench Techniques SHI Rui—Xial，LI Jial，WANG Dong—Zhil，YIN Yan—Shen92 (1．School of Materials Science and Engineering of University of Jinan，Jinan 250022，China；2．School of Materials Science and Engineering of Ocean University of China，Qingdao 266003，China) Abstract：The thermal shock resistance of A1203／TiC(AT)and cobalt—coated A1203／TiC(ATC)compos— ites was measured by the indentation-quench technique．The experimental results show that cobalt—coated A1203／TiC composites exhibit better crack extension resistance and cyclic thermal shock resistance than A1203／TiC，and the critical temperature difference for ATC composites improved 25。C compared with that of the AT composites．Calculated results of thermal shock resistance parameters R，R7，R1V and Rst show that both the resistance to thermal shock fracture and thermal shock damage of ATC composites are better than those of AT．The thermal physic parameters are changed very little but the flexure strength and fracture toughness of ATC composites are improved greatly by introducing 3．96v01％cobalt into AT composites using an electroless method，which contribute to the higher thermal shock parameters．In a word，the better thermal shock resistance should be attributed to the higher flexure strength and fracture toughness of ATC． Key words indentation-quench；thermal shock resistance；cobalt-coated A12 03／TiC