溶液浓度对前驱体FePO4·xH2O及LiFePO4性能的影响.PDFVIP

第 41 卷第 5 期 中南大学学报(自然科学版) Vol.41 No.5 2010 年 10 月 Journal of Central South University (Science and Technology) Oct. 2010 溶液浓度对前驱体 FePO4·xH2O及 LiFePO4性能的影响 彭春丽，沈超，张宝，张佳峰，李倩 (中南大学 冶金科学与工程学院，湖南 长沙，410083) 摘 要：以 NH4H2PO4和 FeSO4·7H2O 为原料，H2O2为氧化剂，通过液相法合成 FePO4·xH2O 前驱体，将 FePO4·xH2O， Li2CO3 和葡萄糖球磨混合以低温固相法合成正极材料 LiFePO4，研究溶液浓度对前驱体 FePO4·xH2O 和 LiFePO4 的影响；采用 X 线衍射(XRD)和扫描电镜(SEM)对样品的晶体结构和形貌进行表征，采用比表面积分析和原子发 射光谱分析等手段比较不同的溶液浓度对产物性能的影响。研究结果表明：当溶液浓度为 0.1，0.3，0.5，1.0 和 1.5 mol/L 时制备的 FePO4·2H2O 均为纯相，在溶液浓度为 1.0 mol/L 时合成的 FePO4·xH2O 含 2 个结晶水，即 x=2； 溶液浓度为 1.0 mol/L 时合成的 FePO4·xH2O 制备的 LiFePO4具有良好的电化学性能；充放电容量为 0.1C(其中，C 为充、放电倍率)首次放电容量达 154.4 mA·h/g，循环 30 次后容量保持率为 99.7%。 关键词：锂离子电池；LiFePO4；前驱体；溶液浓度；电化学性能 中图分类号：TM 912.9 文献标志码：A 文章编号：1672?7207(2010)05?1668?06 Effect of solution concentration on FePO4·2H2O precursor and performance of LiFePO4 PENG Chun-li, SHEN Chao, ZHANG Bao, ZHANG Jia-feng, LI Qian (School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China) Abstract: FePO4·2H2O was prepared by liquid phase method in air using NH4H2PO4, FeSO4·7H2O and oxidant of H2O2 as starting materials. LiFePO4 was synthesized at low temperature with the homogeneous mixture of Li2CO3, glucose and FePO4·2H2O. The structures of FePO4·2H2O and LiFePO4 were characterized by XRD and SEM. The effect of solution concentration on FePO4·2H2O precursor and LiFePO4 was represented by specific surface area and element contents using ICP-AES. The results show that no impurities exist in FePO4·2H2O synthesized with solution concentration from 0.1 mol/L to 1.5 mol/L. LiFePO4/C made from FePO4·2H2O precursor with the solution concentration of 1 mol/L shows excellent electrochemical performance. It has an initial discharge capacity of 154.4 mA·h/g at 0.1C, and capacity retention remains 99.7 % after 30 cycles. Key words：lithium ion batteries; Li