信息检索与阅读：NewCatalystTechnologyforSelectiveOxidationofAromatics精编.pptVIP

The proposed process is also attractive in that, in principle, it produces no by-products. In the cumene 副产品 process, phenol and acetone are produced in equimolar amounts, so the economics of the process 等摩尔数 depends on the marketability of acetone. 新工艺的另一吸引人之处在于，原理上它不产生副产物。 在异丙苯法工艺中，苯酚和丙酮是以等摩尔量产生的，因此该工艺的经济性依赖于丙酮的市场需求量。 This dependence could become a problem when the demand for phenol and acetone are quite different. Currently, the acetone market is over-supplied, and 供过于求 expectations are that it will not grow with the anticipated demand for phenol. 当苯酚和丙酮的需求量存在很大的差异时，这种依赖性就成了问题。 目前，丙酮市场是供过于求的，而且预计它不会随苯酚预期需求量的增加而增加。 In the current project we are investigating a new process for manufacturing phenol from either benzene or toluene by a one-step, heterogeneous catalytic, selective oxidation reaction using molecular oxygen: C6H6 + 1/2O2 → C6H5OH If successful, this one-step process would require much less energy and produce fewer wastes than the conventional process. The proposed process is also attractive in that, in principle, it produces no by-products. In the cumene process, phenol and acetone are produced in equimolar amounts, so the economics of the process depends on the marketability of acetone. This dependence could become a problem when the demand for phenol and acetone are quite different. Currently, the acetone market is over-supplied, and expectations are that it will not grow with the anticipated demand for phenol. 第三部分 在目前的一个项目中，我们正在研究一种以苯或甲苯为原料，通过多相催化以氧气一步氧化制备苯酚的新工艺。如果成功，这种一步法与传统的生产工艺相比需要的能量少的多而且产生很少的污染。新工艺的另一吸引人之处在于，原理上它不产生副产物。在异丙苯法工艺中，苯酚和丙酮是以等摩尔量产生的，因此该工艺的经济性依赖于丙酮的市场需求量。当苯酚和丙酮的需求量存在很大的差异时，这种依赖性就成了问题。目前，丙酮市场是供过于求的，而且预计它不会随苯酚预期需求量的增加而增加。 第三部分 In a joint program with Engelhard Corporation, ABB Lummus, Reaction Design, Northwestern University, and the University of Virginia we are 西北大学 维吉尼亚大学 working on new c