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Radiation grafting of N,N-dimethylaminoethylmethacrylate and
Polymer Bulletin 47, 571-577 (2002)
Polymer Bulletin
? Springer-Verlag 2002
Radiation grafting of N,N-dimethylaminoethylmethacrylate and
4-vinylpyridine onto polypropylene by the one- and two-step methods
E. Bucio, R. Aliev ( ), G. Burillo
Instituto de Ciencias Nucleares, UNAM, Ciudad Universitaria, 04510, Mexico, D.F.
Received: 30 April 2001/Revised version: 21 October 2001/Accepted: 28 November 2001
Summary
Radiation grafting of N,N-dimethylaminoethylmethacrylate (DMAEMA) and 4-
vinylpyridine (4-VP) from the 50% monomers solutions in toluene and dichloroethane
onto polypropylene (PP) films was carried by their mutual γ-irradiation (one-step
method). In the two-step method, the grafting of DMAEMA or 4-VP from their solutions
in toluene was performed onto PP modified preliminary with the other polymer (poly4-
VP or polyDMAEMA). It has been found that chemical structure of PP modified with
the first grafted polymer affected the efficiency of the other monomer grafting by the
second step.
Introduction
In recent years there has been increasing interest in developing novel functional materials
based on the use of strong noncovalent interactions for holding together molecular
components (1-3). The system consists in mixing one functional homopolymer and one
functional compound. The main application of this concept is the design of polymeric
liquid crystalline (LC) materials. It is known that homopolymers obtained from
monomers, containing tertiary amino groups, such as N,N-dimethylaminoethyl-
methacrylate (DMAEMA) or 4-vinylpyridine (4-VP) form salts with several benzoic acid
derivatives but these compounds are often hygroscopic and have poor mechanical
properties (2,3). Therefore preliminary graft polymerization of these monomers onto
hydrophobic and mechanically durable polymer matrices is of interest. Radiation grafting
of DMAEMA onto polyethylene (PE) as well as salts of poly(DMAEMA-g-PE) with
benzoic acids formation were reported earlier (4,5).
Choice of matrices i
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