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NH2CHNH2PbI3 perovskite solar cells with 13.56% efficiency via low temperature processing.pdf

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NH2CHNH2PbI3 perovskite solar cells with 13.56% efficiency via low temperature processing

This journal is? the Owner Societies 2015 Phys. Chem. Chem. Phys., 2015, 17, 19745--19750 | 19745 Cite this:Phys.Chem.Chem.Phys., 2015, 17, 19745 Inverted planar NH2CHQNH2PbI3 perovskite solar cells with 13.56% efficiency via low temperature processing? Da-Xing Yuan,a Adam Gorka,b Mei-Feng Xu,a Zhao-Kui Wang*a and Liang-Sheng Liao*a In this work, NH2CHQNH2PbI3 (FAPbI3) was employed for light harvesting in inverted planer perovskite solar cells for the first time. Except for the silver cathode, all layers were solution-processed under or below 140 1C. The effect of the annealing process on device performance was investigated. The FAPbI3 solar cells based on a slowed-down annealing shows superior performance compared to the CH3NH3PbI3 (MAPbI3)-based devices, especially for the short circuit current density. A power conversion efficiency of 13.56% was obtained with high short circuit current density of 21.48 mA cm2. This work paves the way for low-temperature fabrication of efficient inverted planer structure FAPbI3 perovskite solar cells. Introduction Since organo-metal halide perovskite was first employed for light harvesting in solar cells in 2009,1 much effort has been made to improve device performance, including introducing solid state hole conductors,2 modifying the fabrication process3–10 and the annealing process,11–16 structure engineering,17–19 interface engineering20–30 and so on. So far, the highest performance has overcome 20%.31 However, most work was based on the CH3NH3PbI3 (or CH3NH3PbI3xClx) system, in which its energy bandgap (B1.55 eV) is beyond the ideal bandgap of photo- voltaic materials (1.1–1.4 eV). What’s more, the CH3NH3PbI3 system was reported to have a very low phase transition tem- perature, which will strongly influence the device stability.32 Recently, a brand new perovskite system, known as NH2CHQ NH2PbI3 (FAPbI3) perovskite, has drawn much attention, since it has superior properties compared with the CH3NH3PbI3 (MAPbI3) system, such