Thermophysical properties of ionic liquid {1-butyl-3-methylimidazolium离子液+醇水jct2013.pdf

J. Chem. Thermodynamics 57 (2013) 182–188Contents lists available at SciVerse ScienceDirect J. Chem. Thermodynamics journal homepage: www.elsevier .com/locate / jc tThermophysical properties of ionic liquid {1-butyl-3-methylimidazolium bromide [bmim][Br] in alkoxyalkanols + water} mixtures at different temperatures Amalendu Pal a,?, Harsh Kumar b, Bhupinder Kumar a, Pooja Sharma b, Kirtanjot Kaur b aDepartment of Chemistry, Kurukshetra University, Kurukshetra 136119, Haryana, India bDepartment of Chemistry, Dr B R Ambedkar National Institute of Technology, Jalandhar 144011, Punjab, India a r t i c l e i n f o a b s t r a c tArticle history: Received 26 April 2012 Received in revised form 1 August 2012 Accepted 25 August 2012 Available online 10 September 2012 Keywords: Ionic liquid Alkoxyalkanols Apparent molar volume Adiabatic compressibility Transfer volume Apparent molar expansivity0021-9614/$ - see front matter  2012 Elsevier Ltd. A /10.1016/j.jct.2012.08.023 ? Corresponding author. E-mail address: palchem@ (A. Pal).The interactions of alkoxyalkanols with the ionic liquid 1-butyl-3-methylimidazolium bromide [bmim][Br] as a function of temperature were investigated by combination of volumetric and acoustic methods. The density, q, and speed of sound, u, of ethylene glycol monomethyl ether, diethylene glycol monomethyl ether, and triethylene glycol monomethyl ether (0.00–1.01 molkg1) in aqueous 1-butyl-3- methylimidazolium bromide solutions ranging from pure water to 0.29 mass% of ionic liquid have been measured at T = (288.15, 298.15 and 308.15) K and atmospheric pressure. The apparent molar volume (V/) and adiabatic compressibility (K/,S) of alkoxyalkanols in aqueous ionic liquid solution were deter- mined at the measured temperatures. The partial molar volume eV0/T and partial molar adiabatic com- pressibility eK0uT of alkoxyalkanols at infinite dilution were evaluated. Transfer volumes eDV0/T and transfer adiabatic compressibility (DK0/) at infinite dilutio