EP滴定液配制与标定.docVIP

Volumetric solutions: Hydrochloric acid 盐酸滴定液 1M Hydrochloric acid: Dilute 103.0g of hydrochloric acid R to 1000.0ml with water R. 称取103.0 g 盐酸至1000ml 量瓶中，加水稀释至刻度。 Standardisation: Dissolve 1.000 g of sodium carbonate RV in 50ml of water R, add 0.1 mL of methyl orange solution R and titrate with the hydrochloric acid until the solution just becomes yellowish-red. Boil for 2 min. The solution reverts to yellow. Cool and continue the titration until a yellowish-red colour is obtained. 1 mL of 1 M hydrochloric acid is equivalent to 53.00 mg of Na2CO3. 标定：称取1.000g 基准无水碳酸钠溶解于50ml水中，加0.1ml甲基橙溶液，用盐酸滴定液滴定至溶液出现黄红色。煮沸2分钟。溶液变成黄色。冷却至室温，继续滴定至溶液由黄色变成黄红色。 每1 mL 盐酸滴定液（1mol/L）相当于53.00 mg 无水碳酸钠。 0.1M Hydrochloric acid: Dilute 100.0 mL of 1 M hydrochloric acid to 1000.0 mL with water R. 量取100ml 1 mol/L 盐酸滴定液至1000ml 量瓶中，加水稀释至刻度。 Standardisation. Carry out the titration described for 1 M hydrochloric acid using 0.100 g of sodium carbonate RV dissolved in 20 mL of water R. 1 mL of 0.1 M Hydrochloric acid is equivalent to 5.30 mg of Na2CO3. 标定：按标定1mol/L 盐酸滴定液进行，称取0.100g无水碳酸钠溶于20ml水中。 每1ml 0.1mol/l盐酸滴定液相当于5.30mg碳酸钠。 0.01 M Hydrochloric acid: Dilute 10.0 mL of 1 M hydrochloric acid to 1000.0 mL with water R. 量取10.0mL1mol/L盐酸滴定液并用水稀释至1000.0mL. Standardisation. Sodium hydroxide 氢氧化钠滴定液 1 M sodium hydroxide: 1mol/L氢氧化钠滴定液 Dissolve 42 g of sodium hydroxide R in carbon dioxide-free water R and dilute to 1000.0 mL with the same solvent. 称取42g氢氧化钠，加去二氧化碳水稀释至1000.0ml Standardisation. Titrate 20.0 mL of the sodium hydroxide solution with 1 M hydrochloric acid using the indicator prescribed in the assay in which 1 M sodium hydroxide is used. 标定：量取20.0ml 氢氧化钠溶液，用1mol/L盐酸滴定液标定。使用酚酞指示液指示终点。 0.1M Sodium hydroxide: Dilute 100.0 mL of 1 M sodium hydroxide to 1000.0 mL with carbon dioxide-free water R. 量取1mol/L氢氧化钠滴定液100.0mL，用去二氧化碳水稀释至1000.0mL。 Standardisation. Titrate 20.0 mL of the sodium hydroxide solution with 0.1 M hydrochloric acid, using the end-point detection prescribed for the assay in which th