碳纳米管填料碳纳米管填料静电自组装制备及在导电塑料.PDFVIP

碳纳米管碳纳米管填料填料静电自组装制备及在导电塑料静电自组装制备及在导电塑料中应用中应用 碳纳米管碳纳米管填料填料静电自组装制备及在导电塑料静电自组装制备及在导电塑料中中应用应用 中国科学院成都有机化学有限公司中科时代纳米事业部 摘要摘要 为了提高碳纳米管 （CNTs ）在塑料中的分散性能，设计碳纳米管填料 （CNTs 摘要摘要 Filler ）。阳/非离子表面活性剂复配在水中分散 CNTs，并赋予 CNTs 表面正电性。与 表面负电性的炭黑或聚苯乙烯微球复合，通过静电吸附作用自组装形成均匀稳定的复 合物，制备出 CNTs Filler 。对比了CNTs Filler、CNTs 和炭黑在 PS 和 ABS 塑料中， 经不同成型工艺的导电结果，证明了使用碳纳米管填料提高了碳纳米管在塑料中的分 散性能，总结了碳纳米管相对炭黑作为塑料导电功能体适合压延成型加工。推荐碳纳 米管用于导电片材、导电薄膜和高导电塑料等领域。 关键词关键词 碳纳米管 复合物 复合粉体 静电自组装 导电填料 导电塑料 导静电塑 关键词关键词 料 Carbon Nanotubes Filler Preparaed by Electrostatic Self-assembly and Applicated in Conductive Plastics Chengdu Organic Chemical Co. , Ltd. , Chinese Academy of Sciences, Timesnano Division Abstract In order to improve the dispersion of carbon nanotubes (CNTs) in plastics ，carbon nanotubes filler was prepared. CNTs were dispersed in water promoted by cationic/ non-ionic surfactant. CNTs with positive electricity in surface and carbon black (or polystyrene microsphere) with negative electricity in surface composited together by electrostatic self-assembly to form uniform and stable carbon nanotube filler. The electrical properties of PS and ABS were discussd, with different conductive fillers and different molding process. The unique properties of carbon nanotubes and carbon black as plastic conductive functional medium were summarized. Recommend carbon nanotubes for conductive sheets, conductive films and high conductive plastic, etc 。 Key Word carbon nanotubes complex composite powder electrostatic self-assembly conductive filler conductive plastics static-conductive plastics 0、引言、引言 、、引言引言 碳纳米管（CNTs ）是一维纳米材料的代表，具有大长径比低密度、高强度高模量、 高导电高导热等优异性能，是高分子材料理想的添加剂，是导电塑料理想的导电功能体。 但是 CNTs 还具有表面能高、易团聚易缠绕、难分散的结构特点，成为它在高分子材 料中发挥优异性能的障碍。CNTs 在塑料中的分散程度直接影响导电塑料的性能。借助超 声波设备、借助溶剂介质