FM-50抗冲击改性剂解答.pptVIP

Topics 1. The relation between PVC morphology and physical properties PVC modifier morphology Observation analysis method for morphology TEM DSC Example of the relation between morphology and physical properties in PVC/impact modifier blend system 2. Discoloration of PVC Mechanism of discoloration countermeasure Kane　Ace　FM50 的 特 征 ?　冲 击 强 度 高 耐 候 性 好 光 泽 度 高　 PVC（Kv＝６８）　　 　　　　 １００ｐｈｒ 复合稳定剂（铅） ４．５ｐｈｒ 抗冲击改性剂 变量 加工助剂（Kane　Ace　PA-21） ０．５ｐｈｒ CaCO3 ８．０ｐｈｒ TiO2 ４．５ｐｈｒ b.　单缺口简支梁冲击强度(23℃) c.　焊角强度 2. Discoloration　 Weathering, chemical reaction (acid, alkali, oxidation), thermal reaction PVC ? polyene structure, carbonyl group ? discoloration Pigment shielding UV TiO2(rutile type), carbon black UV absorber Absorb UV and release as heat 2-Hydroxybenzophenones, Tinuvin P etc 耐候性试验(氙灯老化) 3. Summary Morphology and physical properties Physical properties of PVC product are effected by PVC morphology. Adjusting the process condition can enhance physical properties. The morphology of PVCmodifier can be observed by TEM and DSC. Weathering PVC is decomposed by UV and makes discoloration. To protect decomposition, pigment, UV absorber and suitable additives should be selected. * Kaneka Technical Service Co.Ltd (Shanghai) 1-1(1). PVC　morphology 1. The relation between PVC morphology and physical properties primary particle (1μm） Agglomerate（10μm） Droplet（30-50μm） PVC particle（150μm） 10μm 10μm Domain（1000?) Micro domain（100?) molecule Kane　Ace　FM50（丙烯酸类树脂）的构造 核壳结构 约１７０μm 约０．１７μm 甲基丙烯酸 甲酯 丙烯酸类 橡胶 1-1(2). modifier　morphology PVC FM-50 热、剪切 塑化 塑化进行 1-1(3). FM-50与PVC在加工时形态 粉体 粉体 熔融体 熔融体 電子源 試料 lens 透過型電子顕微鏡(TEM) 走査型電子顕微鏡(SEM) 偏光coil 像 CRT ２次電子検出器 分解能 0.5-0.1nm 分解能 2-7nm 1-2. Observation analysis method for morphology Acryl 処理OsO4染色 黒色領域：PVC RuO2染色 薄黒色円状物：FM 濃黒色塊：CaCO3 灰色：PVC 灰色領域：処理剤 窓枠 1-2(1). 透過型電子顕微鏡(TEM) 1-2(2). DSC method measure melt temperature 　 PVC gelation　degree 配方 加工条件 同上 205/205/200/195 高温条件 176/202/202/202/202/206/20