吸附分离辅助电渗透脱水过程中污泥特性的研究于晓艳1，支苏丽2，张书.doc

PAGE  PAGE 8 吸附分离辅助电渗透脱水过程中污泥特性的研究 于晓艳1，支苏丽2，张书廷2，徐晖3 （1天津大学 化工学院，天津300072 2天津大学 环境科学与工程学院，天津300072 3中国人民武装警察部队学院 消防指挥系，廊坊065000） 摘要 电渗透技术对于城市污水厂污泥的深度脱水是非常有效的，但相对较高的能耗制约了它的广泛应用。为此针对污泥电渗透脱水过程中阴极排水困难引起能耗高的问题，本文提出了吸附分离辅助电渗透脱水，同时考察了吸附分离辅助电渗透脱水过程中污泥中水分的运动特点、pH的变化以及离子的迁移规律。结果显示，吸附分离可以极大地提高污泥电渗透脱水的效果。且脱水过程中阳极附近污泥的含水率、pH值均迅速减小；阴极附近污泥的含水率稍有减少，但pH值却迅速增大；而中间层污泥的含水率及pH值均没有发生变化。此外，电渗透脱水技??对于污泥中目标离子的去除非常有效，但同时容易导致非目标离子的去除。 关键词 污泥；电渗透脱水；吸附分离；离子迁移 中图分类号 X705 文献标识码 A Study on characteristics of sludge during electroosmotic dewatering assisted by absorptive separation Yu Xiaoyan1，Zhi Suli1, Zhang Shuting2，Xu Hui3 （1School of Chemical Engineering and Technology, Tianjin University, Tianjin300072, China 2 School of Environmental Science and Engineering, Tianjin University, Tianjin300072, China 3 Department of Fire Commanding, Chinese Peoples Armed Police Forces Academy, Langfang065000, China） Abstract Electroosmosis technique is very effective for deeper dewatering of sludge from municipal wastewater plant, but higher energy consumption has hampered its widespread distribution so far. Aiming to the problem that higher energy consumption caused by the difficulty in the discharge of water accumulated near the cathode, it is proposed that electroosmotic dewatering is assisted by adsorptive separation, and the distribution of water content, pH and ionic electromigration were investigated in this process. The results show that absorptive separation can enhance drastically the electroosmotic dewatering efficiency of sludge. During electroosmotic dewatering assisted by absorptive separation, water content and pH of sludge near the anode decreases sharply, and water content reduces slightly but pH increase rapidly for sludge near the cathode, while those of middle layers keep at initial value. Moreover, elecroosmotic dewatering is effective for target ionic removal in sludge, however, it may be result in the removal of non-target ions. Key words sludge; electroos