纪念王大珩诞辰100周年暨国际光年光耀理工系列学术报.docVIP

纪念王大珩诞辰100周年暨国际光年“光耀理工”系列学术报告会 报 告 人: Dr. Axel Schülzgen 报告题目: Nonlinear Absorption in Acceptor Containing Molecular Species: Searching for Large and Long-lived Nonlinear Absorption 报告时间： 2015年6月17日 ?下午2点—4点 报告地点：东区三教614会议室 主办单位：研究生院 光电工程学院 国际交流合作处 科技处 Abstract：In this talk we will discuss our results on the nonlinear absorption properties of three studies where a centralized acceptor group, typically a squaraine unit, has increased the strength of the nonlinear absorption when compared to similar or identical molecules without it. In the first study, the molecules with the acceptors exhibited a maximum two photon absorption (2PA) cross section approximately 8x that of the same molecule without an acceptor unit. In the following study, a squaraine bridge was used to link two porphyrin molecules together in an attempt to increase 2PA, which is not typically large in porphyrins, and to increase the triplet absorption and intersystem crossing rate, which is not typically found in squaraines. This resulted in a mixed outcome. The 2PA significantly increased compared to their constituents, but the long-lived triplet absorption that was anticipated was very small, not what we were expecting considering there were two porphyrins attached to the squaraine. Finally, a squaraine containing sulfur, a thiosquaraine, was studied, and its nonlinear absorption characterization showed a triplet yield of nearly 100% with a lifetime of almost 250 ns while its counterpart, a typical oxygen containing squaraine, showed no evidence of triplets, in fact showed a fluorescence quantum yield of nearly 100 %. ? About the Speaker： Scott Webster, Ph.D. received his doctorate in physics from Wake Forest University in 2003 investigating the “Optical Characterization of Nanostructured Materials”. From 2004 to present, he has worked at CREOL, the College of Optics and Photonics at the University of Central Florida as a Senior Research Scientist. He has published 62 refer