扩散在金属纳米晶的合成和催化中的应用选编.ppt

一个最清洁的太阳能利用方式，就是光-化学能转化 * * * * * 一个最清洁的太阳能利用方式，就是光-化学能转化 * University of Science and Technology of China Reporters: Yizhen Chen, Hongliang Li Theoretical simulation: Xiaoliang Tang Members: Lingling Wu, Xin Wang, Yanyu Xu May 27th, 2016 * Application of Diffusion in Metal Nanocrystal Synthesis and Catalysis Introduction 1 Diffusion in Synthesis of Nanocrystals 2 Diffusion in Catalysis 3 Summary and Outlook 4 Outline * Introduction Equipotential surface Capacitance of conducting sphere ： A B + e C + e D specific area Size effects： Volcanic curve C9 C15 (110) (111) C4 (100) Activity Selectivity Size Interface Strain Topology Electronic Properties (energy level, orbit, spin) Activation Energy Introduction Design of Metal Nanocrystals Size Science, 2016, 352, 797 Nat. Mater.?2016, 15, 564 Electronic Properties Topology Strain Interface Nano Lett. 2015, 15, 2875 Angew. 2015, 54,108 Introduction Introduction 1 Diffusion in Synthesis of Nanocrystals 2 Diffusion in Catalysis 3 Summary and Outlook 4 Outline * 1.Seeded Growth 2.Kirkendal Effect 3.Combination 4.Theoretical Simulation Diffusion in Synthesis of Nanocrystals * Diffusion in Synthesis of Nanocrystals Diffusion in Seeded growth * Seeded Growth PNAS 2013, 110, 6669 Diffusion vs Deposition Seeded Growth * 22 ℃, Vdeposition/Vdiffusion1 Experimental Conditions 0 ℃, Vdeposition/Vdiffusion 1 50 ℃, Vdeposition/Vdiffusion 1 75 ℃, Vdeposition/Vdiffusion 1 Diffusion in Seeded growth * Kirkendal Effect Kirkendall Effect Nanocale Kirendall Effect Science 2004, 304, 711 * Science 2015, 349, 412 Combination Subnanometer-thick Pt-based Nanocages * Density functional theory（DFT） calculations Combination * Density Functional Theory Calculations Theoretical Simulation * Kirkendal Effect Etching Introduction 1 Diffusion in Synthesis of Nanocrystals 2 Diffusion in Catalysis 3 Summary and Outlook 4 Outline * Hydrogen Diffusion on Metal Surfaces Activation Energy Adsorption Energy Surf. Sci. 2012, 606,