激发态Cs2和H2的电子-振转能级的碰撞转移.pdfVIP

23????1?? 光散射学报 V01??23 No??1 2011??3?? THE JOURNAL ? LIGHT ????? Mar??2011 ???????1004??5929(2011)01??010??05 ??????Cs????H???????????????????????????? 王 青，沈异凡。，戴 康 ?陆?笱?锢砜蒲в爰际跹г海?诼衬酒???? ????????????????????????????????(CARS)??????????????????????Csz??Hz?????????????????? 的碰撞转移。用波长为??龊椭行牟ǔの??帆的两柬激光同时聚焦到样品池中，扫描??谱确 认了?分子的??△口?，△．，??鲈诳??琠???及口?，???能级上有布居，用，?、砌、以?? ????????(2??4)??(2??3)??(1??4)??(1??5)??????????????????CARS??????????????2????l????3????l??????????1???? 为????．?、???縊．?和???縊．?。转移能配置到振动、转动和平动的比例分别为????．?和 ????芰恐饕7峙湓谡穸?推蕉?稀Ｔ赥?? K??Pm=2??5??103?条件下，通过求解速率方程组和 ??????????CARS????????????????????????????????????1??(6??o??1??2)??10-1??cmls_1????=(4??0?? ????????? ??． ????????????????????????????CARS????????????????????????Cs2??H2 ????????????0562??5????????????A The Electronic-t0-RoVibrational ??? ??? ???? between ??????? Excited Cs2 and ? ?? ??，?? ?—???珼? ?? ??罢裀 o??P^ys??Sff????fP????d??P????Zogy??X??????g??i??i???? ????rr??7n??i830046??C??i??z??)) Abstract??Usingthe CARS(coherent ??—??? Raman spectroscopy) detection ??—