Co掺杂对Ni-Mn-Sn铁磁形状记忆合金磁性质的影响.pdfVIP

Trans. Nonferrous Met. Soc. China 24(2014) 1053−1057 Effect of Co substitution on magnetic properties of Ni−Mn−Sn magnetic shape memory alloys 1 1 1 1 2 2 1 Jia-mu CAO , Chang-long TAN , Xiao-hua TIAN , Qin-ci LI , Er-jun GUO , Li-ping WANG , Yi-jiang CAO 1. School of Applied Science, Harbin University of Science and Technology, Harbin 150080, China; 2. School of Materials Science and Engineering, Harbin University of Science and Technology, Harbin 150080, China Received 27 March 2013; accepted 15 October 2013 Abstract: The effect of Co substitution on magnetic properties of Ni−Mn−Sn shape memory alloy was revealed by first-principles calculations. Large magnetization difference in Ni−Mn−Sn alloy obtained by addition of Co arises from enhancement of magnetization of austenite due to change of Mn−Mn interaction from anti-ferromagnetism to ferromagnetism. Total energy difference between paramagnetic and ferromagnetic austenite plays an important role in magnetic transition of Ni−Co−Mn−Sn. The altered Mn 3d states due to Co substitution give rise to difference in magnetic properties. Key words: ferromagnetic shape memory alloys; Ni−Mn−Sn; first-principles calculation; magnetic properties substitution of Co for Ni in Ni−Mn−Sn alloys is an 1 Introduction effective way to increase the difference in magnetization between austenite and martensite phases