Fe2O3含量对CaO-Al2O3-SiO2系微晶玻璃显微组织与力学性能的影响.pdfVIP

Trans. Nonferrous Met. Soc. China 25(2015) 137−145 Effects of Fe O content on microstructure and 2 3 mechanical properties of CaO−Al O −SiO system 2 3 2 Xiang-zhong REN, Wei ZHANG, Yong ZHANG, Pei-xin ZHANG, Jian-hong LIU School of Chemistry and Chemical Engineering, Shenzhen University, Shenzhen 518060, China Received 28 February 2014; accepted 18 June 2014 Abstract: The effects of Fe O content on the microstructure and mechanical properties of the CaO−Al O −SiO system were 2 3 2 3 2 investigated by differential thermal analysis (DTA), X-ray diffraction (XRD), scanning electron microscopy (SEM), electron spin resonance (ESR), and Mössbauer spectroscopy. The results show that the addition of Fe O does not affect the main crystalline phase 2 3 in the prepared glasses, but it reduces the crystallisation peak temperature, increases the crystallisation activation energy, and reduces the crystal granularity. The ESR results indicate that Fe O can promote crystallization, as it leads to the phase separation of the 2 3 CaO−Al O −SiO system due to axial distortion. Moreover, Fe O alters the network structure of the CaO−Al O −SiO system, 2 3 2