PEO-PPO-PEO嵌段共聚物胶团化及其应用研究进展.pdfVIP

! !!!!!!! ! ! 综述与专论 嵌段共聚物胶团化及其 ! ! ! ! ! ! ! ! PEO-PPO-PEO 应用研究进展 苏延磊 郭 晨 刘会洲 （中国科学院过程工程研究所分离科学与工程青年实验室、生化工程国家重点实验室，北京 100080） 摘 要 对 PEO-PPO-PEO 嵌段共聚物在水溶液中形成胶团过程进行了综述 . 阐明了温度、浓度、嵌段共聚物的 分子量和 EO/ PO 比率等因素对 PEO-PPO-PEO 嵌段共聚物的临界胶团浓度、临界胶团温度、胶团的聚集数以及胶 团的结构等的影响 . 简介了小角中子散射、FTIR 光谱、自洽均匀场晶格理论等用于研究 PEO-PPO-PEO 嵌段共聚 物的胶团化机理 . 重点介绍了 PEO-PPO-PEO 嵌段共??物在介孔材料、生化分离、界面吸附、增溶有机物等方面 的应用 . 关键词 PEO-PPO-PEO 嵌段共聚物 胶团化 应用 中图分类号 O 648 文献标识码 A 文章编号 0438 - 1157（2003）04 - 0489 - 08 REVIEW ON MICELLIZATION OF PEO-PPO-PEO BLOCK COPOLYMER IN AOUEOUS SOLUTION AND ITS APPLICATIONS SU Yaniei，GUO Chen and LIU Huizhou （Young Scientist Laboratory of Separation Science and Engineering，State Key Laboratory of Biochemical Engineering， Institute of Process Engineering，Chinese Academy of Sciences，Beijing 100080，China） Abstract The miceiiization properties of PEO-PPO-PEO biock copoiymer in agueous soiution are reviewed. It is ciarified that the factors of temperature，concentration，moiecuiar mass，and EO / PO ratio of the copoiymer infiuence criticai miceiiization concentration，criticai miceiiization temperature，aggregationai number，and miceiiar structure.A brief discription is introduction such as smaii-angie neutron scattering，FTIR spectroscopy，and the seif-consistent mean-fieid iattice theory， which are used to study the mechanism of miceiiization. The appiications of PEO-PPO-PEO biock copoiymer in the syntheseis of mesoporous materiais，the separation of biomacromoiecuies，the adsorption at interface， and the soiubiiization of organics are presented. Keywords PEO-PPO-PEO biock c