“《分析化学》-赛默飞双三元液相色谱应用专刊”征稿启事.pdfVIP

858 分 析 化 学 第 卷 42 π-π GR was adsorbed on apt through the unique stacking interaction, which was further used for the assembly 2+ and signal amplification of the electroactive AQMS. Upon interaction with Pb ions, the apt on the aptasensor undergone conformational switch from a single-stranded form to the G-quadruplex structure, causing the GR assembled with AQMS releasing from the electrode surface into solution. As a result, the electrochemical signal of AQMS on the aptasensor was substantially reduced. Base on this concept, a useful platform for detection of 2+ I pa Pb ions was constructed. Under the optimal experimental conditions, the attenuation of peak currents (△- ) 2+ C 10 Pb2+ showed -linear relationship with the logarithm of Pb concentration-s (lg ) over the range from 5. 0×10 to 8 11 5. 0×10 mol / L. The detection limit was estimated to be 6. 0×10 mol / L. Keywords Lead ion; Aptasensor; Graphene; Anthraquinone-2-sulfonic acid sodium salt (Received 12 September 2013; accepted 4 December 2013) This work was supported by the National Natural Science Foundation of China (No. and the Nationa