一次粒径和二次粒径对LiFePO4性能的影响.pdfVIP

第 27 卷第 5 期 高 校 化 学 工 程 学 报 No.5 Vol.27 2013 年 10 月 Journal of Chemical Engineering of Chinese Universities Oct. 2013 文章编号：1003-9015(2013)05-0884-05 一次粒径和二次粒径对 LiFePO4性能的影响 郭孝东 1,2， 钟本和 1,2， 唐 艳 1, 任建新 1, 胡有坤 1, 刘 恒 3, 方为茂 1 (1. 四川大学 化学工程学院, 四川 成都 610065; 2. 教育部磷资源综合利用与清洁加工工程研究中心, 四川 成都 610065; 3. 四川大学 材料科学与工程学院, 四川 成都 610064) 摘 要：研究了一次粒径和二次粒径对磷酸亚铁锂性能的影响。分别采用扫描电子显微镜(SEM)、激光粒度仪等分析 了材料的一次粒径和二次粒径。将材料装配成扣式电池进行一系列的电化学特性测试，分析磷酸亚铁锂材料的充放电 循环性能、氧化还原电位、阻抗等性能。研究发现一次粒径主要影响磷酸亚铁锂材料的放电容量、放电电位和阻抗， 对材料的振实密度影响视其团聚程度而定；二次粒径对磷酸亚铁锂材料的振实密度影响很大。 关键词：磷酸亚铁锂；一次粒径；二次粒径；影响 中图分类号：TM205.1 文献标识码：A DOI：10.3969/j.issn.1003-9015.2013.05.025 The Influence of Primary Particle Size and Secondary Particle Size on Performances of LiFePO4 GUO Xiao-dong1,2, ZHONG Ben-he1,2, TANG Yan1, REN Jian-xin1, HU You-kun1, LIU Heng3, FANG Wei-mao1 (1. School of Chemical Engineering, Sichuan University, Chengdu 610065, China; 2. Phosphorus Resources Comprehensive Utilization ＆ Clean Processing Center of Ministry of Education, Chengdu 610065, China; 3. School of Materials Science ＆ Engineering, Sichuan University, Chengdu 610064, China) Abstract: The influences of primary particle size and secondary size on the performance of lithium iron phosphate were studied. Scanning electron microscope (SEM) and laser particle size analyzer were employed to characterize the primary particle size and secondary size of lithium iron phosphate samples. The lithium iron phosphate samples were assembled to form the button batteries for the test of the electrochemical features of the samples, such as charge-discharge cycle performance, oxidation-reduction potentials and impedance. At last, it was concluded as following: primary particle size is significant for discharge capacity, discharge potential and impedance except for tap density; the tap