制备方法对添加钇（Y）的非负载型Ni2 P催化剂的影响.pdfVIP

文章编号: 0253-2409(2015)10-1215-06 Received: 2015-06-17; Revised: 2015-09-11. *Corresponding author: Tel: 0453-6984321, E-mail:songhua2004@ sina. com. The project was supported by the National Natural Science Foundation of China , the Natural Science Foundation of Heilongjiang Province (ZD201201), and the Project of Education Department of Heilongjiang Province . 国家自然科学基金, 黑龙江省自然基金(ZD201201)和黑龙江省教育厅面上项目资助 本文的英文电子版由 Elsevier出版社在 ScienceDirect上出版(http: / / www. sciencedirect. com / science / journal / . 制备方法对添加钇(Y)的非负载型 Ni2 P催化剂的影响 李 锋1, 张福勇1, 宋华林2,*, 徐晓伟1, 宋 华1,* (1.东北石油大学 石油与天然气化工省重点实验室, 黑龙江 大庆 163318; 2.牡丹江医学院 医学影像学院, 黑龙江 牡丹江 157011) 摘 要: 采用程序升温还原(T)法和低温次磷酸盐法(L)制备了 Y-Ni2P-T和 Y-Ni2P-L催化剂,并采用 XRD、BET、CO吸附、 XPS等手段对催化剂进行了表征。 以二苯并噻吩(DBT)为模型化合物,研究了稀土 Y对不同方法制备得到的催化剂加氢脱 硫(HDS)性能的影响。 结果表明,对 T法制备的催化剂,添加稀土 Y可以抑制 Ni5P4 杂晶的生成,从而促进活性相 Ni2P的生 成;添加稀土 Y能显著提高催化剂的比表面积,促进小粒径、高度分散的 Ni2P 晶粒的生成。 Y-Ni2P-T 催化剂的 DBT 转化率 达到 91. 0% ,比 Ni2P-T催化剂提高了 29% 。 对 L法制备的催化剂,添加稀土 Y 能抑制其他杂晶的生成,提高了 Y-Ni2P-L 催 化剂对联苯(BP)的选择性,但催化剂的总 HDS活性比 Ni2P-L催化剂略有降低。 关键词: 程序升温还原法; 低温次磷酸盐法; Ni2P; 二苯并噻吩(DBT); 钇(Y) 中图分类号: O643. 361 文献标识码: A Effect of preparation method on the HDS performance of unsupported Y-Ni2P catalysts LI Feng1, ZHANG Fu-yong1, SONG Hua-lin2,*, XU Xiao-wei1, SONG Hua1,* (1. Provincial Key Laboratory of Oil Gas Chemical Technology, Northeast Petroleum University, Daqing 163318, China; 2. Key Laboratory of Cancer Prevention and Treatment of Heilongjiang Province, Mudanjiang Medical University, Mudanjiang 157011, China) Abstract: The Y-Ni2P-T and Y-Ni2P-L were successfully prepared by temperature programmed reduction method (T) and low temperature hypophosphite method (L), respectively. The catalysts were characterized by X-ray diffraction (XRD), N2 adsorption specific surface area measurements (BET), CO uptake, and X-ray photoelectron spectroscopy (XPS) . The effect of the rare earth yttrium (Y) on the HDS activity of catalysts prepared by different met