2007jch 关于Pb-Sn-Sb黄色颜料.pdfVIP

Available online at Journal of Cultural Heritage 8 (2007) 377e386 /direct/CULHER/ Original article Microanalytical identi?cation of Pb-Sb-Sn yellow pigment in historical European paintings and its differentiation from lead tin and Naples yellows David Hradil a,b,*, Toma′sˇ Grygar a,b, Janka Hradilova′ b, Petr Bezdicka a,b, Veronika Grunwaldova} ′ a,b, Igor Fogasˇ c, Costanza Miliani d a Institute of Inorganic Chemistry ASCR, ALMA laboratory, 250 68 Rˇ ez, Czech Republic b Academy of Fine Arts in Prague, ALMA laboratory, U Akademie 4, 170 22 Prague 7, Czech Republic c Moravian Gallery in Brno, Husova 18, 662 26 Brno, Czech Republic d CNR-ISTM and SMAArt, c/o Department of Chemistry, University of Perugia, via Elce di sotto 8, I-06123 Perugia, Italy Received 15 December 2006; accepted 10 July 2007 Abstract The work is focused on identi?cation of lead tin yellow types I and II, Naples yellow, and also on discrimination of a less common, distinct yellow pigment, the ternary Pb-Sb-Sn oxide. The knowledge about all those Pb-based yellows was in fact forgotten after introduction of modern synthetic yellows in 19th century. As late as in the last decade of the 20th century, the existence of Pb-Sb-Sn yellow and its production have been rediscovered, and only then it has been identi?ed in colour layer of artworks. Pb-Sb-Sn yellow has recently been identi?ed in colour layer of 17th century Italian paintings by Sandalinas and Ruiz-Moreno [C. Sandalinas, S. Ruiz-Moreno, Lead tin-antim