吹扫捕集气相色谱质谱法测定水体中54种常见挥发性有机物的研究.pdfVIP

环境污染与防治第 31 卷第 11 期 2009 年 11 月 吹扫捕集/气相包谱/质谱法测定水体中 54 种常见挥发性有机物的研究 孙晓慧 l 吕怡兵 2 潘荷芳 l 刘劲松 1 O. 浙江省环境监测中心，浙江 杭州 310012 ， 2. 中国环境监测总站，北京 100012) 摘要 运用吹扫捕集/气相色谱/质谱 (p ?，. T /GC/MS) 法对水体中 54 种常见的停发做街机物( VOCs) 进行了测定。结果表 明 .VCX汰的包谱分离情况较好，平均加标脱收$为 88.5%-117.0% .相对标准偏毅为 0.71%-8.50% ，准确度和精衔度均符合有 关分析测试的要求:方法检出限为 0.10-0.61 闯/L. 远低于《地发水环境质量标准 (G I:l 3838 … 2002) 、《生洒饮刷水卫生标准 GB 3838 一 2002) 及同外相关你准的限值 ;54 种 VOCs 的线性范网不同，低沸点的 VOCs 线性抱隅较宽，高沸点的 VOCs 的线性很罔较 悟，因此在分析 VOCs 样品配制标准工作曲线时.Iill ìì t:不同沸点 VOCs 的线性范阁。 关键词挥发性有机物 吹妇捕集/气相也谱/质谱法线性范围输出限精密度准确度 1 2 Study on determìnation of S4 kinds of common VOCs by purge and trap-GC/MS Sun Xiaohui ? Lv γihing ? Pan He? 1 1 fang ? Liu J insong ? O. Zhejiang Environmental Monitoring Cent时 ， Hangzhou Zhejiang 310012; 2. China Na? tional Environmental Monitoring Centre. Beijing 100012) Abstr踊ct: More than 190 kinds of volatile organic compounds VOCs) with low content were found in water, which were harmful to the human beings. How to detect trace amount of VOCs accurately and efficiently has become hotspots in nowadays. In this paper, a method was established using purge and trap- gas chromatography / mass spec? trometry (GC/MS) for the determination of 54 kinds of common VOCs in water. The method presented perfect per而 formance in chromatographic separation, linearity, accuracy and precision. Average recoveries for 54 VOCs ranged from 88. 5 % to 117.0 %, and RSDs varied in O. 71 %心. 50 %. Method detection limits (MDLs) were in the range