改性橙皮对水中中性红的吸附及其动力学.PDFVIP

安徽农业大学学报, 2013, 40(3): 514-518 Journal of Anhui Agricultural University 网络出版时间：2013-3-7 17:52:50 [URL] /kcms/detail/34.1162.S1752.027.html 改性橙皮对水中中性红的吸附及其动力学 简绍菊，杨为森 (福建省高校绿色化工技术重点实验室，武夷学院环境与建筑工程系， 武夷山 354300) 摘 要：以生物废料橙皮为原料，经乙醇、NaOH 及 CaCl2 处理，得到改性橙皮生物吸附剂，对中性红染料废 水进行吸附研究，考察了吸附时间、pH 值、染料初始浓度、吸附温度及吸附剂投加量对吸附量的影响及其吸附动 力学。结果表明，在 pH 为 7，改性橙皮用量为 0.1 g，吸附时间为 5 h，吸附温度为 20℃，染料初始浓度为 1 200 mg·L-1 的条件下，改性橙皮对中性红的最大吸附量为 478.60 mg·g-1。改性橙皮对水中中性红的等温吸附平衡符合 Freundlich 吸附等温式，吸附动力学遵循准二级动力学方程。 关键词：橙皮；改性；生物吸附剂；中性红；动力学 中图分类号：X703 文献标识码：A 文章编号：1672?352X (2013)03?0514?05 Adsorption of neutral red by modified flavedo and its biosorption kinetics JIAN Shao-ju, YANG Wei-sen (The Key Laboratory for Green Chemical Engineer Technology of Fujian Higher Education, Department of Environment and Architectural Engineering, Wuyi University, Wuyishan 354300) Abstract: Flavedo was modified by ethanol, sodium hydroxide and calcium chloride for preparing biosor- bent to remove neutral red in waste water. Effects of adsorption time, pH value, initial concentration of dye, tem- perature and absorbent dosage on the adsorption capacity and adsorption kinetics were investigated. In the condi- tions of pH 7, the initial concentration of 1 200 mg·L-1, the dosage of 0.1 g, the contact time for 5 h, the maximum absorption capacity of the modified flavedo could reach 478.60 mg·g-1 at 20℃. The isothermal adsorption fitted for the Freundlich adsorption model. Adsorption kinetics followed by the pseudo- second-order kinetic model. Key words: flavedo; modifi