桐油酰二乙醇胺的制备与表征.PDF

第 5 卷 第 3期 包 装 学 报 Vol.5 No.3 2013 年 7 月 Packaging Journal July2013 doi:10.3969/j.issn.1674-7100.2013.03.001 桐油酰二乙醇胺的制备与表征 王正祥 1，陈亚平 1，王建龙 1，陈 洪 2 （1. 湖南工业大学包装与材料工程学院，湖南株洲 412007； 2. 中南林业科技大学材料科学与工程学院，湖南长沙 410004） 摘 要： 利用桐油和二乙醇胺间的转酰胺基作用制备了桐油酰二乙醇胺，并提出了一种提纯该产物的方 法；同时，运用红外光谱和紫外光谱研究了所得桐油酰二乙醇胺的结构。研究结果显示：纯化后产物的红 外吸收谱带符合桐油酰二乙醇胺分子结构中羟基、酰胺基和共轭双键的特征吸收谱带；桐油酰二乙醇胺和 桐油具有相似的紫外吸收谱带，在 200~270nm 和 283~315nm 处均有强吸收谱带，但受酰胺基和羟基助色团的 影响，桐油酰二乙醇胺的紫外吸收谱带呈现出了一定的红移。 关键词：桐油；桐油酰二乙醇胺；转酰胺基作用 中图分类号：TQ645.8+5 文献标志码：A 文章编号：1674-7100(2013)03-0001-04 Synthesis and Characterization of Tung Oil Acid Diethanolamides Wang Zhengxiang1, Chen Yaping1, Wang Jianlong1, Chen Hong2 （1. School of Packaging and Material Engineering, Hunan University of Technology, Zhuzhou Hunan 412007, China; 2. College of Material Science and Engineering，Central South University of Forestry and Technology, Changsha 410004, China） Abstract ：Tung oil acid diethanolamides was prepared by the transmidation reaction between tung oil and diethanolamine, and a new purification process was put forward. The structure of tung oil acid diethanolamides has been analyzed with Fourier Transform Infrared Spectrometer (FTIR) and Ultraviolet Visible Spectrometer (UV spectrometer). The result shows the characteristic FTIR bands of the product correspond to the relevant bands of tung oil acid diethanolamides, like hydroxyl, acylamino and conjugated double bond; The UV absorption bands of tung oil and tung oil acid diethanolamides are quite similar, both have strong absorption in the range 200~270 nm and 283~315 nm, but the UV absorption bands of tung oil acid diethanolamides present re