Microreactor titanium dioxide - hydrogen peroxide and its synergistic application of photocatalytic degradation.docVIP

 PAGE \* MERGEFORMAT 16 Microreactor titanium dioxide / hydrogen peroxide and its synergistic application of photocatalytic degradation Of: Yemei Ying Li Baoxing Yerong Min Liu Jinhua [Abstract] The use of microfluidic chip titanium dioxide / hydrogen peroxide (TiO2/H2O2) catalysts for photocatalytic degradation of organic compounds and heavy metals analysis of water samples. Microfluidic chip by coating the porous nano-TiO2 in the coating, and the UV LED as the light source, preparation of photocatalytic microreactor. photocatalysis, H2O2 as oxidant, in the light intensity is 80 mW/cm2, a flow rate of 1000 μL / h, H2O2 concentration of 8%, the light reaction time was 19 s conditions, 0.2 mmol / L methylene blue degradation rate of 99.6%. The method is applied to the rich in acidic water samples containing Cd2 + and Zn2 + to the determination of water samples 2.5 g / L of fulvic acid in the 96 s degraded completely within the base, the release of adsorbed Cd2 + and Zn2 +, to achieve accurate measurement. This method is the degradation of high efficiency, secondary pollution, fast, etc., in environmental water samples has a good prospect. [Keywords:] micro-reactor; titanium dioxide; hydrogen peroxide; photocatalytic degradation; environmental analysis 1 Introduction In recent years, UV oxidation of its special decomposition of organic matter, has been widely used in environmental areas such as water treatment and water quality analysis [1,2]. In the UV degradation process such as nano-TiO2 semiconductor often used as a catalyst [1 , 2], and using O2, H2O2, Fe2 +, etc., as photocatalytic oxidants [3,4]. which has a higher H2O2 oxidation potential due not only to play the role of electron acceptors, such as better promotion of strong oxidizing OH substance production [4]. research shows that, TiO2/H2O2 catalyst composition with the most notable performance of photocatalytic degradation [4,5]. Miniaturized lab on a chip with the chemical and life