Parathion in the nano-alumina film modified electrode and its determination on the electrochemical behavior.doc

Parathion in the nano-alumina film modified electrode and its determination on the electrochemical behavior [Abstract] prepared nano-alumina modified glassy carbon electrode (nano Al2O3/GCE/CME, using cyclic voltammetry (CV, linear sweep voltammetry (LSV study parathion (TP) in the nano Al2O3/GCE / The electrochemical behavior of CME. Experiments show that the modified electrode compared with the bare electrode can significantly increase the redox peak current of TP and reduce the oxidation peak potential. In 0  1 mol / L HAc NaAc buffer solution (pH = 5 in , TP in the modified electrode to generate an irreversible reduction peak (Epc1 =- 0  567 V) and 1 pair of reversible redox peaks (Epa2 = 0  018 V and Epc2 =- 0  008 V), the oxidation peak current and TP concentration in the 2  5 × 10-9 ~ 1  0 × 10-7 mol / L and 1  0 × 10-7 ~ 1  0 × 10-5 mol / L range with a good linear relationship , regression equations were: ip (μA) = 0  2529 +4  201C (μmol / L), r = 0  9984 and ip (μA) = 0  6752 +0  3181C (μmol / L), r = 0  9946. 30 s open circuit accumulation, the detection limit of 1  0 × 10-9 mol / L (S / N = 3). In 1  0 × 10-5 mol / L TP Determination of the test solution 10 times in a row, the RSD = 3  8%. determined by the TP content in vegetables, recovery was 95  6% ~ 100  5%, with satisfactory results. [Keywords:] alumina, chemically modified electrode, parathion, electrochemical behavior Abstract The electrochemical behaviors of parathion (PT) on nano Al2O3 film modified electrode (nano Al2O3/GCE/CME) were investigated. It was found that the redox peak currents of PT remarkably increased and the oxidation peak potential negatively shifted at the nano Al2O3 / GCE / CME. All the experimental parameters were optimized and a simple and sensitive electroanalytical method was developed for the determination of PT. The oxidation peak current was linear with the concentration of PT over the range from 2  5 × 10-9 to 1  0 × 10-7 mol / L and 1 