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TiO2 Nanotube Based Dye-sensitized Photoanode 英文论文文献
第 28卷第 5期
2013年 5月
无机材料学报
Vol. 28 No. 5
May, 2013
Journal of Inorganic Materials
文章编号: 1000-324X(2013)05-0521-06
DOI: 10.3724/SP.J.1077.2013.12368
基于二氧化钛纳米管的染料敏化电池光阳极研究
罗华明, 刘志勇, 白传易, 鲁玉明, 蔡传兵
(上海大学物理系,上海 200444)
摘 要:本文报道了一种基于二氧化钛 (TiO2)纳米管的染料敏化太阳能电池。用二次阳极氧化法在钛箔上生长出高
度有序的 TiO2纳米管薄膜,然后将完整剥落的纳米管薄膜结合 TiO2纳米颗粒的浆料转移到掺杂氟的 SnO2透明导
电玻璃(FTO)基底上,从而获得一种特殊的染料敏化光阳极。对比了不同长度的 TiO2纳米管的电池性能 ,发现经
TiCl4处理长度为 32.8 μm的 TiO2纳米管对应的电池表现较好的光电转换效率 ,达到 4.15%。通过 X射线衍射分析
了高温退火对纳米管晶化结构的影响。电化学阻抗谱分析表明 :光电子传输对光阳极纳米管层厚依赖性强 ,随着纳
米管长度的增长 ,界面电阻呈明显的减小 ,这一结果对于理解和进一步改善染料敏化电池光阳极内部电子输运过
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