温度和压力对泥页岩吸附性能的影响.docVIP

Sustainable Energy 可持续能源, 2012, 2, 28-30 /10.12677/se.2012.21005 Published Online January 2012 (/journal/se) The Effect of Temperature and Pressure on Shale Adsorption Capability Shaobin Guo, Yinsen Sun, Yigang Wang, Zuxin Xu School of Energy Resources, China University of Geosciences, Beijing Email: guosb58@126.com Received: Nov. 10th, 2011; revised: Dec. 9th, 2011; accepted: Dec. 13th, 2011. Abstract: In order to study the effect of both temperature and pressure on shale adsorption capability, this paper se- lected organic-rich shale samples of Upper Paleozoic Taiyuan formation in Ordos Basin and then made isothermal ad- sorption test of difference temperature for shale sample. Based on the test data, the isothermal adsorption curves were established at different temperature points. Research is discovered that the shale adsorption quantity are decreased with increasing temperatures under isotonic condition. Affection of pressure is greater than temperature for shale adsorption under the integrated influence of temperatures and pressures in lowness temperature and pressure area, the adsorption quantity of shale are increased with temperature and pressure. Affection of temperature is greater than pressure for shale adsorption in higher temperature and pressure area, the adsorption quantity of shale is decreased. Keywords: Isothermal Adsorption; Temperature; Pressure 温度和压力对泥页岩吸附性能的影响 郭少斌，孙寅森，王义刚，徐祖新 中国地质大学(北京)能源学院，北京 Email: guosb58@126.com 收稿日期：2011年 11月 10日；修回日期：2011年 12月 9日；录用日期：2011年 12月 13日 摘 要：为了研究不同温度和压力共同对泥页岩吸附性能的影响，本文通过选取鄂尔多斯盆地上古生界太原组 富有机质泥页岩样品进行了不同温度下的等温吸附实验，得到不同温度点的等温吸附曲线。研究发现，在等压 条件下，泥页岩吸附甲烷气量随着温度的增加呈线性减少，在温度和压力的综合作用下，在较低温度和压力区， 压力对泥页岩吸附能力的影响大于温度的影响，随着温度和压力的增加泥页岩吸附甲烷气量增大；在较高温度 和压力区，温度对泥页岩吸附能力的影响大于压力的影响，泥页岩吸附甲烷气量减少。 关键词：等温吸附；温度；压力 1.引言 之一。页岩气是指以吸附和游离状态赋存于富有机质 泥页岩地层中，具有商业价值的生物成因和热成因的 非常规天然气。由于泥页岩中所含的溶解气量极少， 故页岩气总资源量可近似分解为吸附气总量与游离 随着我国国民经济快速发展，对能源、尤其是清 洁能源的需求持续增加。目前在我国一次性能源消费 结构中天然气所占比例远低于世界平均水平。为进一 步缓解我国油气的供需矛盾，积极寻找新