硼酸活化碳酸钾溶液吸收CO.docVIP

Hans Journal of Chemical Engineering and Technology 化学工程与技术, 2012, 2, 103-107 /10.12677/hjcet.2012.24018 Published Online October 2012 (/journal/hjcet.html) Study on CO Absorption with Aqueous Potassium Carbonate 2 Solution Promoted by Boric Acid* Shufeng Shen , Xiaoxia Feng # Hebei Research Center of Pharmaceutical and Chemical Engineering, School of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang # Email: shufengshen@ Received: Aug. 8 , 2012; revised: Sep. 3 , 2012; accepted: Sep. 10 , 2012 th rd th Abstract: The addition of promoter into aqueous potassium carbonate solution is one of the effective ways to enhance the CO absorption rate. In this work, the CO absorption rates were investigated for aqueous carbonate solution pro- 2 2 moted by different addictives in a wetted wall column. The effect of concentration of boric acid on the overall gas-phase mass transfer coefficient and vapor-liquid equilibrium data was discussed. Results showed that the addition of boric acid can significantly enhance the CO absorption rate. The overall mass transfer coefficient increased by 80% with the 2 addition of 3 wt% boric acid. CO partial pressure increased with the increasing temperature of aqueous potassium car- 2 bonate. However it decreased when boric acid was added, which would be favorable for CO absorption. 2 Keywords: Carbon Dioxide Absorption; Potassium Carbonate; Boric Acid; Vapor-Liquid Equilibrium 硼酸活化碳酸钾溶液吸收 CO的研究* 2 # 申淑锋，冯晓霞 河北科技大学化学与制药工程学院，河北省药物化工工程技术研究中心，石家庄 Email: shufengshen@ # 收稿日期：2012年 8月 8日；修回日期：2012年 9月 3日；录用日期：2012年 9月 10日 摘 要：加入活化剂是提高碳酸钾溶液吸收 CO 速率的有效方法。在湿壁柱中研究不同活化碳酸钾溶液吸收 CO2 2 的效果基础上，考察了不同硼酸浓度对碳酸钾吸收 CO 速率的影响，测定了活化液的气液平衡数据。结果表明 2 加入硼酸能够明显提高 CO 吸收速率，3 wt%硼酸可将总传质系数提高约 80%；碳酸钾溶液随着温度升高 CO2 2 平衡分压升高，加入硼酸后比相同条件下碱液的 CO 平衡分压略低，有利于二氧化碳吸收。 2 关键词：