有机化合物波谱解析课件 综合练习题及答案_第2套.pdfVIP

SPECTRUM ELUCIDATION HEBEI UNIVERSITY OF SCIENCE AND TECHNOLOGY Comprehensive Exercises 2 Try to do the exercises by yourself, then go to the answers and think why. Problem 1. Which one of the C H isomers shown has its λ at the longest 5 8 max wavelength ? Answer Problem 2. In the solution of hexane, the absorption maximum of a compound is at 305nm, whereas in aqueous solution the absorption maximum is at 307nm. The n→π* transition or the π→π* , which leads to the absorption ? Answer The absorption band which is made by π→π* transition . Problem 3. Which can you indentify each of the following compounds to absorb in the IR spectrum and give the reasons? (1) CH CH CH OH and CH CH NHCH 3 2 2 3 2 3 (2) and O (3) CH3C CCH3 and CH CH C CH 3 2 (4) CH CH CH OCH and CH CH COCH 3 2 2 3 3 2 3 Answer (2) (3) (4) Problem 4. Indicate which of the two given compounds is responsible for the IR spectrum? (1) (2) OH O 1 / 6 SPECTRUM ELUCIDATION HEBEI UNIVERSITY OF SCIENCE AND TECHNOLOGY Answer (2) O Problem 5. How many signals would you expect to find in the H NMR spectrum of the following compound 1-Bromobutane? Answer To test for chemical-shift equivalence. Replace the protons at C-1.