有机化合物波谱解析课件 紫外光谱部分习题及答案.pdfVIP

    UV problems 1.In the solution of methanol , the absorption maximum is at 284nm. Which is the structure of the compound, A or B? CH3 H C 3 O O O O H C H C 3 3 OH OH A B Answer A 2. Which one of the C H isomers shown has its λ at the longest wavelength? 5 8 max Answer 3.Compares the λ and ε of the the following compounds: max max Ethylene; 1,3,5-hexatriene; 1,3-butadiene Answer 1,3,5-hexatriene 1,3-butadiene Ethylene 4. Compares the λmax of the following compounds and give the reasons. Answer dcab 5. How would you use UV to distinguish the following isomers? H HC C C CH2 H H H C C C CH2 H a b   1 / 2        HC CH2 HC CH2 c d CH CH CH CH 2 3 2 3 Answer aλ =254nm.; bλ =219nm ; cλ =268nm ; dλ =298nm . max max max max 6. For each of the following pairs of compounds, indentify which has the longer λmax? CH3