介孔沸石材料.pdfVIP

第 20 卷 第 5 期 化 　学 　进 　展 Vol . 20 No . 5 2008 年 5 月 PROGRESS IN CHEMISTRY 　May , 2008 介孔沸石材料 王德举 　刘仲能 　李学礼 　谢在库 ( 中国石油化工股份有限公司上海石油化工研究院　上海 201208) 摘 　要 　介孔沸石材料是含有丰富介孔的结晶沸石 ,不仅保留了沸石材料优良的酸性和水热稳定性 ,而 且由于介孔的引入改善了其对大分子的吸附和扩散性能 ,在催化领域特别是涉及大分子的催化反应中是极 有应用前景的材料 。本文综述了介孔沸石材料的制备方法并进行了比较分析 ,概述了近年来介孔沸石材料 在不同催化反应中的应用 ,探讨了介孔沸石材料今后的研究方向。 关键词 　介孔 　沸石 　吸附　扩散 　催化 ( ) 中图分类号 : O6433 ; TB383 　文献标识码 : A 　文章编号 : 1005281X 2008 Mesoporous Zeolite Materials Wang Dej u 　L iu Zhongneng 　L i X ueli 　X ie Zaiku ( Shanghai Research Institute of Petrochemical Technology , SINOPEC , Shanghai 201208 , China) Abstract 　Mesoporous zeolite materials , which are defined as the crystalline zeolite materials containing a large amount of mesopores , not only inherit excellent acidity and hydrothermal stability of zeolite , but also improve the adsorption and diffusion of large molecules due to the insertion of mesopores. Mesoporous zeolite materials have much effective and promised applications in catalysis , especially catalytic reaction involving large molecules. In this article we summarize several methods for the preparation of mesoporous zeolite materials and show their differences. Recent applications of mesoporous zeolite materials in different catalytic reactions are introduced and further research areas of mesoporous zeolite materials are discussed . Key words 　mesopores ; zeolite ; adsorption ; diffusion ; catalysis 　　无机多孔材料具有较大的比表面积和孔容 ,在 术以及分子工程等方面具有广泛的用途 ,近年来一