Catalytic Activity of ZrO2 Nanotube Arrays Prepared by Anodization Method英文文献资料.docVIP

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Catalytic Activity of ZrO2 Nanotube Arrays Prepared by Anodization Method英文文献资料.doc

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Catalytic Activity of ZrO2 Nanotube Arrays Prepared by Anodization Method英文文献资料

HindawiPublishingCorporation JournalofNanomaterials Volume2012,ArticleID409571,5pages doi:10.1155/2012/409571 ResearchArticle CatalyticActivityofZrO2NanotubeArraysPreparedby AnodizationMethod XixinWang,JianlingZhao,XiaoruiHou,QiHe,andChengchunTang SchoolofMaterialScienceandEngineering,HebeiUniversityofTechnology,Tianjin300130,China CorrespondenceshouldbeaddressedtoJianlingZhao,zhaojl02@ Received24March2011;Revised13May2011;Accepted5June2011 AcademicEditor:MohammadRezaBayati Copyright?2012XixinWangetal.ThisisanopenaccessarticledistributedundertheCreativeCommonsAttributionLicense, whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkisproperlycited. ZrO2 nanotube arrays were prepared by anodization method in aqueous electrolyte containing (NH4)2SO4 and NH4F. The morphologyandstructureofnanotubearrayswerecharacterizedthroughscanningelectronmicroscope,X-raydi?raction,and infraredspectraanalysis.Thezirconiananotubearrayswereusedascatalystinesteri?cationreaction.Thee?ectsofcalcination temperatureandelectrolyteconcentrationoncatalyticesteri?cationactivityhavebeeninvestigatedindetail.Experimentsindicate thatnanotubearrayshavehighestcatalyticactivitywhentheconcentrationof(NH4)2SO4is1mol/L,theconcentrationofNH4 Fis 1wt%,andthecalcinationtemperatureis400 conditions. ? C.Esteri?cationreactionyieldofasmuchas97%couldbeobtainedunderoptimal 1.Introduction incatalysis?eld.Inthispaper,ZrO2 nanotubearrayspre- paredbyanodizationmethodintheelectrolytecontaining ZrO2,duetoitsexcellentphysicalandchemicalproperties, iswidelyusedincatalysis?eld.Forexample,itcanbeused as catalyst or catalyst carrier in Fischer-Tropsch synthesis, polymerization,isomerization,alkylationandesteri?cation reaction,andsoforth[1–4].Inaddition,itcanalsobeused in environment and energy aspects including synthesis of biodieselandcatalyticpuri?cationofharmfulgas[5–9]. ThestructureandmorphologyofZrO2havesigni?cant e?ect on its catalytic activity. ZrO2 nanoparticles can im- prov