钛基金属氧化物阳极的制备及其对有机物废水处理的-上海师范大学学报.doc

钛基金属氧化物阳极的制备及其有机物的研究随着社会工业化水平的不断提高，工业废水的产生与处理，如不妥善处理，有害物质会使生态平衡和自然资源遭到破坏，人民健康受到影响。电化学方法以其规模可控，操作方便，无选择性等特点。 DSA电极使其具备其他支撑功能。为了使用电化学氧化方法对模拟苯酚废水进行降解，制备了锰锑掺杂的钛基SnO2电极，以期能延长电极寿命，提高降解效率。通过SEM，XRD，循环伏安曲线，强化寿命测试等方法，对电极进行表征和分析，并对影响因素进行了系统研究。 关键词：钛基金属氧化物阳极；有机物废水；苯酚；电化学氧化；降解 Study on the preparation of titanium based metal oxide anodes and the treatment of organic wastewaters Cheng Xu, Hongru Tian, Yongshai Zhai, Jie Liang* (College of Life and Environmental Sciences, Shanghai Normal University, Shanghai 200234, China) Abstract With the rapid development of improvement of the social industrialization, the threat of industrial wastes to the environment is becoming more and more obvious. If not treated properly, the harmful substances will destroy the ecological balance and natural resources and severely affect peoples health. Recently, electrochemical method has been widely concerned due to its scale controllability, convenient operation, and non-selectivity. Our purpose is to modify the anode according to the different requirements，the electrode structure can be modified to endue it other supporting functions for more application. Our research aims to degrade phenol in the wastewater by a high efficient electrochemical method. In this paper, Mn and Sb doped Ti-based SnO2 (Ti/ MnO2/SnO2-Sb) electrode was prepared. Its degradation ability towards organic pollutants was improved and its life time was prolonged via optimizing the electrode preparation process. The as-prepared Ti/MnO2/SnO2-Sb anode was characterized and analyzed using SEM, XRD, cyclic voltammetry, and enhanced life test. The factors affecting the degradation of organic compounds were systematically studied. The results show that the activity and stability of the doped DSA electrode are greatly improved, compared to those of the unmodified electrode. The oxygen evolution potential of the doped DSA electrode was up to 2.3V and its accelerated life was up to 42 h. For the treatment of wastewater containing 10