有机胺催化酯交换合成聚碳酸酯树脂工艺.pdfVIP

学兔兔 化 工 进 展 2010年第29卷第1期 CHEMICAL INDUSTRY AND ENGINEERING PR0GRESS ·67· 有机胺催化酯交换合成聚碳酸酯树脂工艺 赵贺猛，田恒水 (华东理工大学化工学院，上海 200237) 摘 要：研究了以碳酸二苯酯 (DPC)和双酚A(BPA)为原料，氢氧化四乙基铵 (TEAH)为催化剂，熔融酯交 换合成聚碳酸酯的工艺。其催化剂用量、原料配比、反应时间等3-艺奈件对产物分子量等参数有较大的影响。与 以氢氧化钠作催化剂相比，在所得的较优条件下以TEAH为催化剂，可得到分子量较高、分子量分散指数低、熔 体流动性好、支化重排产物少、基本无色的聚碳酸酯树脂。 关键词：聚碳酸酯；熔融酯交换；有机胺 中图分类号：TQ 323．4l 文献标识码：A 文章编号：1000—6613(2010)0I一0067—05 Synthesis of polycarbonate through melt transesterification process catalyzed with organic amine ZHA0 Hemeng，TIANHengshui (Department of Chemical Engineering，East China University of ScienceTechnology，Shanghai 200237，China) Abstract：The synthesis of polycarbonate(PC)by melt transesterification from diphenol carbonate (DPC)with 4,4-dihydroxy-diphenyl一2，2一propane(BPA)using tetraethyl ammonium hydroxide(TEAH) as catalyst was experimentally studied．The properties of the resulting polymer was influenced markedly by the operating conditions including the concentration of catalyst，the ratio of DPC／BPA and reaction times in different processing stages．Compared with NaOH，using TEAH as catalyst under the optimized process conditions，an almost colorless PC was obtained with relatively higher molecular weight， narrower molecular weight distribution and less branching and rearranging side—products． Key words：polycarbonate；melt transesterification organic amine 聚碳酸酯 (polycarbonate)是一种性能卓越的 剂后，反应速率可大大提高，目前工业上主要采用 工程塑料类高分子树脂，因其特有的力学和光学性 NaOH做催化剂L2J，催化速率较高，但会发生较多 能，被广泛应用于航空航天、汽车制造、医疗食品、 的重排反应，使PC高分子链产生不可预测的支化 电子电器、光学制品