浆态床中CO2加氢直接合成二甲醚的双功能催化剂.pdfVIP

学兔兔 化 工 进 展 2009年第28卷第8期 CHEMICAL INDUSTf AND ENGD旺 ERD G PROGRESS ·1365· 浆态床中Co2加氢直接合成二甲醚的双功能催化剂 别良伟，王 华，高文桂，王翠芳 (昆明理工大学材料与冶金学院，云南 昆明650093) 摘 要：采用共沉淀沉积法制备了CuO—ZnO．A12O3一ZIO2／HZSM一5双功能催化剂，利用XRD、BET、H2一TPR、 NH3．TPD等手段进行表征。在连续流动加压浆态床反应器中，以医用石蜡为惰性液相介质，研究了其对CO2加 氢直接合成二甲醚的催化反应，考察了不同温度、不同压力、不同氢碳比和不同空速对反应结果的影响。研究表 明，提高反应温度有利于提高CO2转化率，但使二甲醚的选择性降低；增大压力和氢碳比有利于提高CO2转化率 和二甲醚的选择性；增大空速会使CO2转化率和二甲醚选择性均呈现下降趋势。 关键词：二氧化碳；二甲醚；双功能催化剂；浆态床 中图分类号：O 643 文献标识码：A 文章编号：1000—6613(20o9)O8—1365—06 Hybrid catalysts for the direct synthesis of dimethyl ether from carbon dioxide hydr0genati0n in a slurry reactor BIELiangwei，WANG Hua，GAO Wengui，WANG Cuifang (Faculty of Materials and Metallurgical Engineering，Kunming University of Science and Technology，Kunming 650093， Yunnan，China) Abstract：CuO—ZnO—A1203-ZrO2／HZSM一5 hybrid catalysts were prepared by a coprecipitation sedimentation method for the direct synthesis of dimethyl ether(DME)from CO2 hydrogenation．The prepared catalysts were characterized by XRD．BET,HE—TPR and NH3一TPD techniques．The hydrogenation process was carded out in a continuous flow pressurized slurry reactor using medical paraffin as a fiquid medium under different temperature，pressure，H21CO2 molar ratio and space gas velocity．砀e increase in reaction temperature is beneficial to improve the conversion of CO2．while the selectivity for DME is decreased．The increase in pressure and H2／CO2 molar ratio Can improve both the conversion of CO2 and the selectivity for DME． 1hi1e，the increase in the space velocity would decre