HMS催化甲苯液相氧化制苯甲醛.pdfVIP

学兔兔 化 工 进 展 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2012年第3 1卷第7期 Cr(]II)／HMS催化甲苯液相氧化制苯甲醛 吴娟娟，孟利芬，毛丽秋，尹笃林 (资源精细化与先进材料湖南省高校重点实验室，湖南师范大学精细催化合成研究所，湖南 长沙 410081) 摘 要：以溶胶．凝胶法合成的HMS分子筛为载体，采用浸渍法制备了一系列的Cr(III)／HMS负载型催化剂。考 察了不同铬源、负载量对甲苯液相双氧水氧化制备苯甲醛的影响，并利用XRD、FTIR技术对催化剂进行了表征。 结果表明，铬离子已经进入到载体HMS的骨架。以硝酸铬为铬源，铬负载量为15％的催化剂效果最好，甲苯的 转化率为20．8％，苯甲醛的选择性达31．7％。并对甲苯液相氧化的反应机理作了初步的探讨。 关键词：Cr(III)／IIMS；甲苯；液相氧化；苯甲醛 中图分类号：0643 文献标志码：A 文章编号：1000—6613(2012)07—1512—05 Liquid—phase oxidation of toluene to benzaldehyde on Cr(]II)／HMS catalyst WUJuanjuan，MENGLifen，MAOLiqiu，YINDulin (Key Lab ofResources Fine-Processing andAdvanced Materials ofHunan Province，Institute ofFine Catalysis and Synthesis， Hunan Normal University，Changsha 410081，Hunan，China) Abstract：Cr(III)／IIMS catalysts were prepared by the impregnation method using Cr(NO3)3 as chromium source supported on HMS synthesized by the sol—gel method．The catalysts were characterized by XRD and FTIR．The effect of loading content of Cr and different chromium sources on liquid phase oxidation of toluene to benzaldehyde with H202 was investigated．The results showed that chromium ion was incorporated into the framework of HMS．Cr(III)／HMS catalyst with Cr-loading of 1 5％ gave the best catalytic activity．The conversion of toluene and the selectivity for benzaldehyde reached 20．8％and 3 1．7％respectively~A reaction mechanism is proposed． Key words：Cr(III)／HMS；toluene；liquid-phase oxidation；benzaldehyde 甲苯的氧化产物苯甲醛是一种具有广泛用途的 转化率低等缺点。因此，寻找一种高效的催化剂具 精细化工中间体，用于医药、染料