HZSM-5在CO2加氢合成二甲醚中的性能影响.pdfVIP

学兔兔 化 工 进 展 ·542· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 201 1年第30卷第3期 Ce助剂对CuO．ZnO．AI2O3／HZSM．5在CO2加氢合成 二甲醚中的性能影响 张 跃，李 静，严生虎，刘建武，沈介发 (常州1大学精细化工研究所，江苏 常州 213164) 摘 要：采用凝胶网格共沉淀法制备二甲醚的催化剂CuO—ZnO—A1203／HZSM一5，考察不同助剂La、Ce、Co、Zr 对其性能的影响。结果表明，加入助剂后，CO2转化率和二甲醚的选择性都有不同程度的提高，进行比较后发现 尤其是加入Ce助剂后，二甲醚的选择性达到61．5％，CO，的转化率达到40％。利用BET、XRD、SEM、H，．TPR、 H2一TPD等表征方法对其物化性质进行表征。 关键词：二甲醚；CO2加氢；明胶网格共沉淀法；铈 (Ce)；助剂 中图分类号：O 643．38 文献标志码：A 文章编号：1000—6613(2011)03—0542—05 Effect of Ce loading in CuO--ZnO--AI203／HZSM--5 on catalytic performance of dimethyl ether synthesis from carbon dioxide ZHANG Yue，LIJing，YANShenghu， Jianwu，SHENJiefa (Research Institute of Fine Chemical Engineering，Changzhou University，Changzhou 213164，Jiangsu，China) Abstract：CuO--ZnO—-A1203 was prepared by gel--network CO--precipitation for synthesizing dimethyl ether from carbon dioxide by hydrogenation and the effects of La，Ce，Co and Zr promoters on catalyst performance were investigated．The results showed that after adding a small amount of Ce，the selectivity of dimethyl ether reached 61．5％ and the conversion rate of C0，reached 40％．The physical—chemical propertise and catalytic performance of the catalysts were characterization by using BET，XRD，SEM ，TPR and HE—TPD techniques． Key words：dimethyl ether；carbon dioxide hydrogenation；gel—network CO—precipitation method； cerium (Ce)：promoter 二甲醚 (DME)具有低沸点、汽化热大、对环 合成气法[9 刚，甲醇脱水法虽然产率高但由于其操 境无污染、毒性小等优点，是氟利昂的理想代