MgO助剂对CH4／CO2重整反应Ni／BaTiO3催化剂性能的影响.pdfVIP

维普资讯 学兔兔 化 T 进 展 ·724· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2008年第27卷第5期 MgO助剂对CH4／CO2重整反应Ni／BaTiO3催化剂性能的影响 廖卫兵 ，曹小华 ( 江西新余高々太阳能科学与工 系，江西 新余33803 1； 江两九汀学院化学化工学院，江西 九江332005) 摘 要：采用分步浸渍法制备了MgO改性的Mg—Ni／BaTiO3催化剂，考察了MgO助剂对催化剂性能的影响，运 用H2一TPR、XRD、BET等测试技术对催化剂进行表征，并与催4LCf,J Ni／BaTiO3、Ni／y-A1203比较。发现MgO的 添加有利于提高催化Of,J的催化活性和抗积炭性能；适量的MgO助利可以改善催化剂的性能，但过量的MgO却会 对催化剂的性能产生不良影响，随着MgO含量的增加，反应活性基本呈下降趋势。同时研究了不同的制备方法 对催化剂催化活性的影响，用溶胶一凝胶法制备的催化荆具有更高的催化活性。 关键词：Ni；BaTi0 ；MgO；重整；载体 中图分类号：0 643 文献标识码：A 文章编号：l000—6613(2008)05—0724—05 Effect of MgO promoter on properties of Ni／BaTiO3 catalyst for CH4／COz reforming to syngas LIAO Weibing ，CA0Xiaohua ( Depaament ofSolar Energy Science and Engineering，Xinyu College，Xinyu 338031，Jiangxi，China： School of Chemistry and Chemical Engineering，Ji@ang College，Jiujiang 332005，Jiangxi，China) Abstract：The effect of MgO promoter on the physico—chemical properties and catalytic performance of Mg—Ni／BaTiO3 catalyst for CH4／CO2 reforming to syngas were studied with H2一TPR，BET and XRD．It was found that Mg—Ni／BaTiO3 catalyst with a proper amount of MgO promoter showed higher catalytic activity and stronger resistance to carbon deposition than Ni／BaTiO3 and Ni／7一A1203．However， excessive MgO promoter exerted a negative effect on catalyst perform ance，with increasing content of MgO，the reactivity of catalysts decreased．The effect of preparation methods on catalytic activity was also studied，and the results showed that the c