SEG浪潮及其思考.pdfVIP

学兔兔 化 工 进 展 2014年第33卷增刊1 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS · 123 · — {进展与述i,：tz 2 ． — — ． —。 ! SEG浪潮及其思考 张婕 ，孙书培 ，张秀全。，蒋元力 ，张浩勤 ( 郑州大学化工与能源学院，河南 郑州 450001； 河南煤业化工集团研究院，河南郑州 450046) 摘 要：与石油制乙二醇 (MEG)相比，煤制乙二醇 (SEG)在原料路线、反应机制和能耗等方面都具有优势， 国内掀起了SEG项目的建设浪潮。草酸酯法合成SEG是普遍采用的路线，但国内外许多研究机构使用的核心技 术有别，并相应建设了生产线，目前国内SEG建设呈现出百家争鸣状态。但是，工业化过程表明SEG的关键技 术和工艺还有待进一步突破。本文综述了乙二醇 (EG)的合成方法及生产路线，着重介绍了SEG浪潮，并对 SEG的建设和发展中存在的问题提出了几点思考，以期能对国内SEG的发展提供一些有益的建议。 关键词：煤制乙二醇；石油制乙二醇；稳定性；标准；聚酯 Construction wave and thoughts of SEG ZHANG Jie ，SUN Shupei ，ZHANG Xiuquan ，JIANG Yuanli ，ZHANG Haoqin ( School of Chemical Engineering and Energy，Zhengzhou University，Zhengzhou 450001，Henan。China； Research Institute of Henan Coal Chemical Industry Group Co．，Ltd．，Zhengzhou 450046，Henan，China) Abstract：SEG has more advantages than MEG in terms of raw material routes，reaction mechanism and energy consumption．So，a construction wave of SEG proj ects has started in China．Synthesis of EG via procedure of oxalate is the widely used route，but the core technologies of different research institutes are different and various production lines are built． However，the process of industrialization of SEG indicated that breakthrough of key technologies and processes remains to be made． This paper reviews the synthesis methods and production 1ines of EG。 and focuhe SEG construction wave． Some thoughts on the problems in the construction and development of SEG are put forward，hoping to provide some useful suggestions for the development of domes