无溶剂煤沥青粉填充聚氨酯防水材料制备和性能.pdfVIP

学兔兔 化 工 进 展 ·18l2· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2008年第27卷第l1期 无溶剂煤沥青粉填充聚氨酯防水材料制备和性能 李万捷 ，杨 晋 ，耿 露 ，姚润生2王志忠 ( 太原理工大学化学化工学院，山西 太原 030024； 山西金尧焦化有限公司，山西 临汾 041000) 摘 要：以高温煤沥青粉为填料，聚氨酯为基料，研究了高温煤沥青粉含量、煤沥青粉粒径等条件对聚氨酯防水 材料力学性能、透水性及低温弯折等性能的影响，并通过扫描电镜分析了煤沥青粉及防水材料的微观形态和相互 作用机理：通过TG、DSC讨论了该防水材料的耐热特性及低温脆性温度。结果表明，煤沥青粉含量在10％～15％ 时可满足国家标准规定的防水材料要求，煤沥青粉粒径越小，材料力学性能越好，且具有良好的耐热特性及耐低 温性能。 关键词：聚氨酯；煤沥青粉；防水材料 中图分类号：TQ 323．8；TU 561．65 文献标识码：A 文章编号：1000—6613(2008)11—1812—04 Preparation and properties of polyurethane—coal pitch powder waterproof material without solvent L／Wanjie ，YANGJin ，GENGLu ，YAORunsheng。，WANGZhizhong ( School of Chemistry and Chemical Engineering，Taiyuan University of Technology，Taiyuan 030024，Shanxi China； Shanxi Jinyao Coking Corp．，Linfen 041000，Shanxi，China) Abstract：Coal pitch powder as filler was added to polyurethane in order to prepare a waterproof materia1．The mechanical properties，waterproof performance and cryogenic flexibility were determined and the influence of such factors as coal pitch powder’s content and particle size on the waterproof material properties was investigated．Additionally，the interaction mechanism between coal pitch powder and polyurethane was investigated by studying the micro--morphology of the water--proof material with SEM．The measurements of the heat—resistance and temperature of the waterproof material were carried out respectively by TG and DSC．The result indicated that the properties of the waterproof material can satisfy all the requirements of Chinese N