双（氟代磺酰）亚胺及其盐的制备、性能与应用进展.pdf

学兔兔 化 工 进 展 2011年第30卷第10期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·2097· 双 (氟代磺酰)亚胺及其盐的制备、性能与应用进展 胡锋波，张庆华，詹晓力，陈丰秋 (浙江大学化学工程与生物工程学系，浙江 杭州 310027) 摘 要：双 (氟代磺酰)亚胺及其盐具有独特的结构和性能，在锂二次电池、离子液体、催化剂等领域引起了 广泛的关注。本文综述了该类化合物的制备方法，比较了各类方法的优缺点；从分子结构上分析了该类化合物 某些碱金属盐含有结合水的原因，并归纳了目前合成无水型碱金属盐的方法；综述了它们作为锂二次电池的电 解质使用时的各项性能；最后介绍了它们的应用进展，并指出了今后的研究重点及方向。 关键词：双 (氟代磺酰)亚胺；锂盐；电导率；热稳定性 中图分类号：O 646．1 文献标志码：A 文章编号：1000—6613(2011)10—2097—09 Synthesis，performance，and application progress of bis(fluoro·based sulfony1)imides and their salts HUFengbo，ZHANG Qinghua，ZHANXiaoli，CHENFengqiu (Department ofChemical and Biochemical Engineering，Zhejiang University，Hangzhou 310027，Zhejiang，China) AbstractDue to their unique structure and performance，bis(fluoro．based sulfony1)imides and their salts’have attracted increasing interests in the fields of lithium—based rechargeable batteries，ionic liquids，and catalysts，et a1．In this paper，preparation methods of these compounds are reviewed，and their advantages and disadvantages are compared．The reason of some alkali metal salts combined with hydration water is analyzed from their molecular structures，and preparation methods of anhydrous alkali—metal salts are alSO summarized．Their performance is introduced when they are used as electrolytes of lithium—based rechargeable batteries．At last，their application progress is presented，and the research emphases and development trend are discussed． Key wordsbis(fluoro—based sulfony1)imide；lithium salts；conductivity；thermal stability 在化石能源被过度开采，并由此引发能源危 性极强的BrCnsted酸，由于