合成气制混合燃料醇的研究进展.pdfVIP

学兔兔 化 工 进 展 2015年第34卷第5期 CHEMICAL INDUSTRy AND ENGINEER／NG PROGRESS ·1269· 合成气制混合燃料醇的研究进展 宗弘元，马宇春，刘仲能 (中国石化上海石油化工研究院，上海 201208) 摘要：合成气直接转化制混合燃料醇等清洁燃料是能源化工领域的研究热点，过程涉及醇合成和费托合成步 骤，体系非常复杂，而高性能催化剂和高效分离工程的开发是混合燃料醇工艺大规模应用的关键技术。本文 综述了合成气制混合燃料醇的典型反应工艺和当前催化剂的最新研究进展，系统总结了改性甲醇合成、改性 费托合成、硫化物及其他类型催化剂体系的研究现状，指出通过调控活性相结构与组成、提高催化剂稳定性 和产物中混合醇的选择性是合成气制混合醇催化剂的发展方向，提出了通过多反应、多过程耦合实现合成气 定向转化制混合醇及C，+醇的应用前景。 关键词：合成气；混合醇；工艺；催化剂 中图分类号：O 643．36 文献标志码：A 文章编号：1000—6613(2015)05—1269—08 DoI：10．16085~．issn．1000-6613．2015．05．O15 Research progress of higher alcohols synthesis from syngas ZONGHongyuan，MA Yuchun，LIUZhongneng (Shanghai Research Institute ofPetrochemical Technology，SINOPEC，Shanghai 201208，China) Abstract：The conversion of syngas to mixed higher alcohols has attracted much attention in the field of energy and chemical engineering during the past decades．High performance catalysts and efficient separation process are key technologies for industrial large—scale application．This paper summarizes the latest research progress of process and catalyst for higher alcohols synthesis，in which catalytic systems including modified methanol catalysts，modified Fischer-Tropsch catalysts， MoS2 based catalysts and other catalysts are well reviewed．A promising route to improve catalytic perform ance in mixed higher alcohols synthesis is proposed by controlling the structure and composition of catalyst precisely，SO as to increase stability and selectivities．The trend of conversion of syngas to mixed higher alcohols directly is also suggested by