大孔树脂对竹叶总黄酮的吸附平衡和动力学.pdfVIP

学兔兔 化 工 进 展 ·2158· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 201 1年第30卷第10期 大孑L树脂对竹叶总黄酮的吸附平衡和动力学 康家胜，方 菊，魏凤玉，杨艳明 (合肥工业大学化学工程学院，安徽 合肥 230009) 摘 要：考察了7种大孔树脂对竹叶总黄酮的吸附及解吸特性，发现AB一8大孔树脂具有较高的吸附选择性和良 好的脱附性能，并采用静态吸附实验研究了AB一8大孔树脂对竹叶总黄酮的吸附平衡和动力学特性。结果表明， Freundlich方程可较好地描述竹叶总黄酮在AB一8树脂上的吸附平衡；吸附自由能变AG0，熵变AS0，吸附为自 发的熵增过程，升高温度有利于吸附分离。焓变△H为 13．45 kJ／mol，在氢键键能范围内；吸附竹叶总黄酮前后 树脂的红外谱图也表明，AB一8树脂对竹叶总黄酮分子的吸附是以氢键形式发生的物理吸附。动力学研究表明， 吸附过程符合二级动力学方程，颗粒外的液膜扩散是决定吸附速率的主要步骤。 关键词：竹叶总黄酮；AB一8树脂；吸附平衡；动力学 中图分类号：O 647．31；TQ 465．5 文献标志码：A 文章编号：1000—6613(2011)10—2158—06 Adsorption equilibrium and kinetics of bamboo flavonoids on AB一8 resin KANGJiasheng，FANGJu，WE1Fengyu，YANG Yanming (School of Chemical Engineering，Hefei University of Technology，Hefei 230009，Anhui，China) Abstract：Seven types of macroporous resin were selected to compare their performances in adsorbing and desorbing bamboo flavonoids．AB一8 macroporous resin showed high selectivity and good desorption property．Static sorption experiments were carried out to study the adsorption equilibrium and kinetics of bamboo flavonoids on AB一8 macroporous resin at different temperatures．The results indicated that Freundlich equation was the best for the description of the adsorption equilibrium of bamboo flavonoids on AB一8 resin，the negative value of AG and the positive value of AS showed that the adsorption was a spontaneous process of increased entropy，and the increase of temperature would benefit the adsorption process．The adsorption heat AH was 13．45 kJ／mol within the range of hydrogen bond energy；and the FT—IR